การพัฒนาความสัมพันธ์ระหว่างความหนาแน่นและน้ำหนักโมเลกุล ของกรดไขมันเมทิลเอสเทอร์
Keywords:
Fatty acid methyl ester, Density, Molecular Weight, BiodieselAbstract
Density is the physical properties of fuel and dependent on temperature. It is important for the combustion system processing in the diesel engine. Hence, this research aims to develop the relationship equation of the density and molecular weight of fatty acid methyl ester (FAME) at different temperatures by using the Gibbs energy additivity method (GEAM). In this study that was used the density of FAME and biodiesel of 365 data to calibrate the equation. It was found that the equation can be used to estimate the density of FAME and
biodiesel at temperature range of 278.15 – 313.15 K with is a good agreement of AAD
References
Habrioux, M., Freitas, S. V. D., Coutinho, J. o. A. P. and Daridon, J. L. (2013). High Pressure Density and Speed of Sound in Two Biodiesel Fuels. J. Chem. Eng. Data. 58. 3392−3398.
Xue, J., Grift, T. E. and Hansen, A. C. (2011). Effect of biodiesel on engine performances and emissions. Renewable and Sustainable Energy Reviews. 15. 1098–1116.
Zarska, M., Bartoszek, K. and Dzida, M. (2014). High pressure physicochemical properties of biodiesel components derived from coconut oil or babassu oil. Fuel. 125. 144–151.
Dzida, M. and Prusakiewicz, P. (2008). The effect of temperature and pressure on the physicochemical properties of petroleum diesel oil and biodiesel fuel. Fuel. 87. 1941–1948.
Moser, B. R. (2009). Biodiesel production, properties, and feedstocks. In Vitro Cell.Dev.Biol.—Plant. 45. 229–266.
Hoekman, S. K., Broch, A., Robbins, C., Ceniceros, E. and Natarajan, M. (2012). Review of biodiesel composition, properties, and specifications. Renewable and Sustainable Energy Reviews. 16. 143– 169.
Chum-in, T., Sudaprasert, K., Phankosol, S., Lilitchan, S., Aryusuk, K. and Krisnangkura, K. (2016). Gibbs energy additivity approaches to QSPR in modeling of high pressure dynamic viscosity of FAME and biodiesel. Journal of Molecular Liquids. 223. 1006-1012.
Chum-in, T., Sudaprasert, K., Phankosol, S., Lilitchan, S., Aryusuk, K. and Krisnangkura, K. (2016). Gibbs energy additivity approaches to QSPR in modeling of high pressure density and kinematic viscosity of FAME and biodiesel. Fuel Processing Technology.
Krisnangkura, K., Aryusuk, K., Phankosol, S. and Lilitchan, S. (2016). Energy Additivity Approaches to QSPR Modeling in Estimation of Dynamic Viscosity of Fatty Acid Methyl Ester and Biodiesel. Journal of the American Oil Chemists' Society.
Phankosol, S., Sudaprasert, K., Lilitchan, S., Aryusuk, K. and Krisnangkura, K. (2014). Estimation of Density of Biodiesel. Energy and Fuels. 28. 4633−4641.
Phankosol, S., Sudaprasert, K., Lilitchan, S., Aryusuk, K. and Krisnangkura, K. (2015). An Empirical Equation for Estimation of Kinematic Viscosity of Fatty Acid Methyl Esters and Biodiesel. J Am Oil Chem Soc. 92. 1051-1061.
Phankosol, S., Sudaprasert, K., Lilitchan, S., Aryusuk, K. and Krisnangkura, K. (2014). Estimation of surface tension of fatty acid methyl ester and biodiesel at different temperatures. Fuel. 126. 162–168.
Krisnangkura, K., Yimsuwan, T. and Pairintra, R. (2006). An empirical approach in predicting biodiesel viscosity at various temperatures. Fuel. 85. 107–113.
Martin, A. J. P. (1950). Some theoretical aspect of partition chromatography. Biochem. Soc. Sym. (Partition Chromatography). 3. 4−20.
Krisnangkura, K., Sansa-ard, C., Aryusuk, K., Lilitchan, S. and Kittiratanapiboon, K. (2010). An empirical approach for predicting kinematic viscosities of biodiesel blends. Fuel. 89. 2775–2780.
Srisaipet, A., Aryusuk, K., Lilitchan, S. and Krisnangkura, K. ( 2007). The relationship between vapour pressure, vaporization enthalpy, and enthalpy of transfer from solution to gas: An extension of the Martin equation. J. Chem. Thermodynamics. 39. 1077–1084.
Ramírez Verduzco, L. F. (2013). Density and viscosity of biodiesel as a function of temperature: Empirical models. Renewable and Sustainable Energy Reviews. 19. 652-665.
Anand, K., Ranjan, A. and Mehta, P. S. (2010). Predicting the Density of Straight and Processed Vegetable Oils from Fatty Acid Composition. Energy Fuels. 24. 3262–3266.
Pratas, M. J., Freitas, S. V. D., Oliveira, M. B., Monteiro, S. l. C., Lima, A. l. S. and Coutinho, J. o. A. P. (2011). Biodiesel Density: Experimental Measurements and Prediction Models. Energy & Fuels. 25. 2333-2340.
Pratas, M. J., Freitas, S., Oliveira, M. B., Monteiro, S. C., Lima, A. l. S. and Coutinho, J. a. A. P. (2011). Densities and Viscosities of Minority Fatty Acid Methyl and Ethyl Esters Present in Biodiesel. Journal of Chemical & Engineering Data. 56. 2175–2180.
Fisher, C. (1988). Evaluating and Predicting N-Fatty Acid Properties. Journal of American Oil Chemists' Society. 65. 1647-1651.
Freitas, S. V. D., Pratas, M. J., Ceriani, R., Lima, A. l. S. and Coutinho, J. o. A. P. (2011). Evaluation of Predictive Models for the Viscosity of Biodiesel. Energy & Fuels. 25. 352-358.
Pratas, M. J., Freitas, S., Oliveira, M. B., Monteiro, S. l. C., Lima, A. l. S. and Coutinho, J. o. A. P. (2011). Densities and Viscosities of Minority Fatty Acid Methyl and Ethyl Esters Present in Biodiesel. Journal of Chemical & Engineering Data. 56. 2175-2180.
Giakoumis, E. G. (2013). A statistical investigation of biodiesel physical and chemical properties, and their correlation with the degree of unsaturation. Renewable Energy. 50. 858-878.
Knothe, G. and Steidley, K. R. (2005). Kinematic viscosity of biodiesel fuel components and related compounds. Influence of compound structure and comparison to petrodiesel fuel components. Fuel 84. 1059–1065.
Ramos, M. J., Fernández, C. M., Casas, A., Rodríguez, L. and Pérez, Á. (2009). Influence of fatty acid composition of raw materials on biodiesel properties. Bioresource Technology. 100. 261–268.
Ramírez-Verduzco, L. F., Rodríguez-Rodríguez, J. E. and Jaramillo-Jacob, A. d. R. (2012). Predicting cetane number, kinematic viscosity, density and higher heating value of biodiesel from its fatty acid methyl ester composition. Journal/Fuel. 91(102–111.
Felipe, L. and Ramı´rez-Verduzco. (2013). Density and viscosity of biodiesel as a function of temperature: Empirical models. Renewable and Sustainable Energy Reviews. 19. 652–665.
Ramírez-Verduzco, L. F., García-Flores, B. E., Rodríguez-Rodríguez, J. E. and Jaramillo-Jacob, A. d. R. (2011). Prediction of the density and viscosity in biodiesel blends at various temperatures. Fuel. 90. 1751–1761.
Ashraful, A. M., Masjuki, H. H., Kalam, M. A., I.M., F. R., S., I., S.A., S. and H.M., M. (2014). Production and comparison of fuel properties, engine performance, and emission characteristics of biodiesel from various non-edible vegetable oils. Energy Conversion and Management. 80. 202-228.
Atabani, A. E., A.S.Silitonga, H.C.Ong, T.M.I.Mahlia, H.H.Masjuki, Badruddin, I. A. and H.Fayaz. (2013). Non-edible vegetable oils:Acritical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engineperformance and emissions production. Renewable and Sustainable Energy Reviews. 18. 211–245.
Pratas, M. J., Freitas, S., Oliveira, M. B., Monteiro, S. l. C., Lima, A. S. and Coutinho, J. o. A. P. (2010). Densities and Viscosities of Fatty Acid Methyl and Ethyl Esters. J. Chem. Eng. Data. 55. 3983–3990.
Baroutian, S., Shahbaz, K., Mjalli, F. S., Hashim, M. A. and AlNashef, I. M. (2012). Densities and Viscosities of Binary Blends of Methyl Esters + Ethyl Esters and Ternary Blends of Methyl Esters + Ethyl Esters + Diesel Fuel fromT= (293.15 to 358.15) K. Journal of Chemical & Engineering Data. 57. 1387-1395.
Parente, R. C., Nogueira, C. A., Carmo, F. R., Lima, L. P., Fernandes, F. A. N., Santiago-Aguiar, R. S. and de Sant'Ana, H. B. (2011). Excess Volumes and Deviations of Viscosities of Binary Blends of Sunflower Biodiesel + Diesel and Fish Oil Biodiesel + Diesel at Various Temperatures. Journal of Chemical & Engineering Data. 56. 3061-3067.
Carlos A. Nogueira, J., Feitosa, F. X., Fabiano A. N. Fernandes, Santiago, R. l. S. and Sant’Ana, H. B. d. (2010). Densities and Viscosities of Binary Mixtures of Babassu Biodiesel + Cotton Seed or Soybean Biodiesel at Different Temperatures. J. Chem. Eng. Data. 55. 5305–5310.
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