Fabrication of Activated Carbon Pouch Cell Supercapacitor: Effects of Calendering and Selection of Separator-Solvent Combination
Article Sidebar
Main Article Content
Abstract
Most published articles reported characterization of a supercapacitor utilizing a coin cell or a Swagelok cell design, while the higher capacity format such as a pouch or cylindrical cell is needed to predict the performance of a supercapacitor for a practical application. In this work, the guideline to produce a pouch cell supercapacitor is given. The three-component electrode is based on a commercially available activated carbon, carbon black, and a polyvinylidene fluoride binder, which is formed a layer on a conductive-carbon coated aluminum foil current collector. The roles and optimization of a calendering process and selection of a separator-solvent combination are highlighted. The symmetric electric double-layer capacitor (EDLC) pouch cell using organic salt electrolyte is rated at 2.5 Volt. The pouch cell has the maximum capacitance of 32.6 F with a specific capacitance of 25.6-29.4 F/g.
Keywords: supercapacitor; pouch cell; electric double-layer capacitor (EDLC); activated carbon; organic electrolyte
*Corresponding author: E-mail: [email protected]
Article Details
Copyright Transfer Statement
The copyright of this article is transferred to Current Applied Science and Technology journal with effect if and when the article is accepted for publication. The copyright transfer covers the exclusive right to reproduce and distribute the article, including reprints, translations, photographic reproductions, electronic form (offline, online) or any other reproductions of similar nature.
The author warrants that this contribution is original and that he/she has full power to make this grant. The author signs for and accepts responsibility for releasing this material on behalf of any and all co-authors.
Here is the link for download: Copyright transfer form.pdf
References
Al-Hallaj, S., Wilke, S. and Schweitzer, B., 2017. Energy storage systems for smart grid applications. In: A. Badran, S. Murad, E. Baydoun and N. Daghir, eds. Water, Energy & Food Sustainability in the Middle East. Cham, Switzerland: Springer.
Vazquez, S., Lukic, S.M., Galvan, E., Franquelo, L.G. and Carrasco, J.M., 2010. Energy storage systems for transport and grid applications. IEEE Transactions on Industrial Electronics, 57(12), 3881-3895.
Hannan, M.A., Hoque, M.M., Mohamed, A. and Ayob, A., 2017. Review of energy storage systems for electric vehicle applications: Issues and challenges. Renewable and Sustainable Energy Reviews, 69, 771-789.
Horn, M., MacLeod, J., Liu, M., Webb, J. and Motta, N., 2019. Supercapacitors: A new source of power for electric cars?. Economic Analysis and Policy, 61, 93-103.
Mejdoubi, A.E., Chaoui, H., Gualous, H., Oukaour, A., Slamani, Y. and Sabor, J., 2016. Supercapacitors state-of-health diagnosis for electric vehicle applications. World Electric Vehicle Journal, 8(2), 379-387.
Muyeen, S.M., Shishido, S., Ali, M.H., Takahashi, R., Murata T. and Tamura, J., 2007. Application of energy capacitor system to wind power generation. Wind Energy, 11(4), 335-350.
Maxwell Technologies. Document number: 3000615-EN.2. [online] Available at: https://www.maxwell.com/images/documents/Ultracapacitors_Overview_Flyer_3000615-2EN.pdf
Soltani, M., Ronsmans, J., Kakihara, S., Jaguemont, J., Bossche, P.V., Mierlo, J. and Omar, N., 2018. Hybrid battery/lithium-ion capacitor energy storage system for a pure electric bus for an urban transportation application. Applied Sciences, 8, 1176.
Iro, S.Z., Subramani, C. and Dash, S.S., 2016. A brief review on electrode materials for supercapacitor. International Journal of Electrochemical Science, 11, 10628-10643.
Pandolfo, A.G., Wilson, G.J., Huynh, T.D. and Hollenkamp, A.F., 2010. The influence of conductive additives and inter‐particle voids in carbon EDLC electrodes. Fuel Cells, 10(5), 856-864.
Böckenfeld, N., Jeong, S.S., Winter, M., Passerini, S. and Balducci, A., 2013. Natural, cheap and environmentally friendly binder for supercapacitors. Journal of Power Sources, 221, 14-20.
Zhong, C., Deng, Y., Hu, W., Qiao, J., Zhang, L. and Zhang, J., 2015. A review of electrolyte materials and compositions for electrochemical supercapacitors. Chemical Society Reviews, 44, 7484-7539.
Zhong, C., Deng, Y., Hu, W., Sun, D., Han, X., Qiao, J. and Zhang, J., 2016. Compatibility of Electrolytes with Inactive Components of Electrochemical Supercapacitors. In: Electrolytes for Electrochemical Supercapacitors. [online] Available at: https://www. routledgehandbooks. com/doi/10.1201/b21497-4
Arora, P. and Zhang, Z., 2004. Battery separators. Chemical Reviews, 104, 4419-4462.
Liu, X., Dai, X., Wei, G., Xi, Y., Pang, M., Izotov, V., Klyui, N., Havrykov, D., Ji, Y., Guo, Q. and Han, W., 2017. Experimental and theoretical studies of nonlinear dependence of the internal resistance and electrode thickness for high performance supercapacitor. Scientific Reports, 7, 45934.
Dsoke, S., Tian, X., Täubert, C., Schlüter, S. and Wohlfahrt-Mehrens, M., 2013. Strategies to reduce the resistance sources on electrochemical double layer capacitor electrodes. Journal of Power Sources, 238, 422-429.
Bhattacharjya, D., Carriazo D, Ajuria, J. and Villaverde, A., 2019, Study of electrode processing and cell assembly for the optimized performance of supercapacitor in pouch cell configuration. Journal of Power Sources, 439, 227106.
Masarapu, C., Wang, L.P., Li, X. and Wei, B., 2012. Tailoring electrode/electrolyte interfacial properties in flexible supercapacitors by applying pressure. Advanced Energy Materials, 2, 546-552.
Roberts, A.J., 2019. Effect of time, temperature and potential on pre-conditioning of supercapacitors. In: ECS Meeting Abstract, The Electrochemical Society, p. 116.
Robertsa, A.J., Rubioa, I., Gonzalezb, D. and Bhagata, R., 2016. Supercapacitors: From coin cell to 800 F pouch cell. In: ECS Meeting Abstract, The Electrochemical Society, p. 1029.
Rubioa, I., Gonzaleza, D., Stoevab, Z., Lowa, J.C.T. and Robertsa, A.J., 2017. Development and Testing of Large Format Graphene Supercapacitors, in: Meeting Abstract, The Electrochemical Society, p. 595.
Azais, P., Tamic, L., Huitric, A., Paulais, F. and Rohel, X., 2016. Separator Film, Its Fabrication Method, Supercapacitor, Battery and Capacitor Provided with Said Film, US. Pat. 9,461,288.
Xiamen Tob New Energy Technology Co., Ltd. Specifications: 25um PP Film Battery Separator for Lithium Battery Research. [online] Available at: https://tob.en.alibaba.com
Morita, M., Noguchi, Y., Tokita, M., Yoshimoto, N., Fujii, K. and Utsunomiya, T., 2016. Influences of residual water in high specific surface area carbon on the capacitor performances in an organic electrolyte solution. Electrochimica Acta, 206, 427-431.
Haselrieder, W., Ivanov, S., Christen, D.K., Bockholt, H. and Kwade, A., 2012. Impact of the calendering process on the interfacial structure and the related electrochemical performance of secondary lithium-ion batteries. ECS Transactions, 50(26), 59-70.
Liu, W., Dang, Y., Xie, W. and Tang, A., 2019. Weakening of mechanical properties of cellulose separator caused by electrolyte immersion and elevated temperature. Polymer Composites, 40(10), 3857-3865.