Effect of Carbonization Temperature on Physical Properties and Specific Capacitance of Activated Carbon Derived from Banana Stem and Its Application as Supercapacitor Electrodes

Main Article Content

Paweena Dulyaseree*
Hasanee Sama
Suraida Sada
Pundita Ukkakimapan
Visittapong Yordsri
Vichuda Sattayarut
Winadda Wongwiriyapan

Abstract

In this work, activated carbons (ACs) for electrodes supercapacitor applications were successfully synthesized from banana stem. Banana is one of the popular fruits that is easy to grow and most parts of the plant can be used.  However, banana cultivation generates a lot of wastes, especially from the stem. Thus, using banana stem as raw material for ACs was investigated. The synthesis of AC consisted of 2 processes; carbonization and activation. The advantage of a two-step synthesis was the low weight loss of charcoal. Firstly, the carbonization process was conducted by varying the temperature between 300-600°C, and then inorganic elements were removed by treatment with 1 M sulfuric acid. After that, activation was conducted at 720°C under an argon atmosphere. The electrochemical properties of banana stem-derived ACs (BCH-ACs) were studied using sodium sulfate as an electrolyte. The BCH-ACs carbonized at 400°C showed the highest performance with a specific capacitance of 55.45 Fg-1, an energy density of 7.70 Whkg-1 and a power density of 133.94 Wkg-1. The highest specific capacitance of the BCH400-AC was likely due to the increase in the amount of oxygenated functional group, which facilitated the access of electrolyte ions into the electrode. These results suggest that banana stem can be used to synthesize ACs via carbonization at 400°C, and the ACs generated can be applied as electrode in supercapacitors.


Keywords: banana stem; activated carbon; supercapacitor


*Corresponding author: E-mail: [email protected]

Article Details

Section
Original Research Articles

References

Li, K., Fu, S., Zhan, H., Zhan, Y. and Lucia, L., 2010. Analysis of the chemical composition and morphological structure of banana pseudo-stem. BioResources, 5, 576-585.

Aziz, N.A.A., Ho, L-H., Azahari, B., Bhat, R., Cheng, L-H. and Ibrahim, M.N.M., 2011. Chemical and functional properties of the native banana (Musaacuminata×balbisiana Colla cv. Awak) pseudo-stem and pseudo-stem tender core flours. Food Chemistry, 128(3), 748-753.

Sango, T., Cheumani, A.M., Duchatel, L., Marin, A., Kor, N.M. and Joly, N., 2018. Step-wise multi-scale deconstruction of banana pseudostem (Musa acuminata) biomass and morpho–mechanical characterization of extracted long fibres for sustainable applications. Industrial Crops and Products, 122, 657-668.

Padam, B.S., Tin, H.S., Chye, F.Y. and Abdullah, M.I., 2014. Banana by-products: An under-utilized renewable food biomass with great potential. Journal of Food Science and Technology, 51, 3527-3545.

Ahmad, T. and Danish, M., 2018. Prospects of banana waste utilization in wastewater treatment: A review. Journal of Environmental Management, 206, 330-348.

Abdullah, N., Sulaiman, F., Miskam, M.A. and Taib, R.M., 2014. Characterization of banana (Musa spp.) pseudostem and fruit-bunch-stem as a potential renewable energy resource. International Journal of Biological, Veterinary, Agricultural and Food Engineering, 8, 712-716.

Khalil, H.S.A., Alwani, M.S. and Omar, A.K.M., 2007. Chemical composition, anatomy, lignin distribution, and cell wall structure of Malaysian plant waste fibers. BioResources, 1(2), 220-232.

Arie, A.A., Kristianto, H., Demir, E. and Cakan, R.D., 2018. Activated porous carbons derived from the Indonesian snake fruit peel as anode materials for sodium ion batteries. Materials Chemistry and Physics, 217, 254-261.

Kurniawan, A., Suwandi, A.C., Lin, C.X., Ismadji, X.S. and Ong, L.K., 2012. A facile and green preparation of durian shell-derived carbon electrodes for electrochemical double-layer capacitors. Progress in Natural Science: Materials International, 22, 624-630.

Chen, X., Zhang, J., Zhang, B., Dong, S. and Guo, X., 2017. A novel hierarchical porous nitrogen-dopedcarbon derived from bamboo shoot for high performance supercapacitor. Scientific Reports, 7, DOI: 10.1038/s41598-017-06730-x.

Lee, D., Cho, Y.G., Song, H.K., Chun, S.J., Park, S.B. and Choi, D.H., 2017. Coffee-driven green activation of cellulose and its use for all-paper flexible supercapacitors. ACS Applied Materials & Interfaces, 9, 22568-22577.

Chen, H., Yu, F., Wang, G., Chen, L., Dai, B. and Peng, S., 2018. Nitrogen and sulfur self-doped activated carbon directly derived from elm flower for high-performance supercapacitors. ACS Omega. 3, 4724-4732.

Liang, T., Chen, C., Li, X. and Zhang, J., 2016. Popcorn-derived porous carbon for energy storage and CO2 capture. Langmuir, 32, 8042-8049.

Dulyaseree, P., Fujishige, M., Yoshida, I., Toya, Y., Banba, Y., Tanaka, S., Aoyama, T., Phonyiem, M., Wongwiriyapan, W., Takeuchi, K. and Endo, M., 2017. Nitrogen-rich green leaves of papaya and Coccinia grandis as precursors of activated carbon and their electrochemical properties. RSC Advance, 7, 42064-42072.

Sattayarut, V., Wanchaem, T., Ukkakimapan, P., Yordsri, V., Dulyaseree, P., Phonyiem, M., Obata, M., Fujishige, M., Takeuchi, K., Wongwiriyapan, W., Endo, M., 2019. Nitrogen self-doped activated carbons via the direct activation of Samanea saman leaves for high energy density supercapacitors. RSC Advance, 9, 21724-21732.

Ukkakimapan, P., Wanchaem, T., Yordsri, V., Sattayarut, V., Phonyiem, M., Fujishige, M., Takeuchi, K. and Wongwiriyapan, W., 2020. Investigation on electrochemical properties of sugarcane leaves-derived activated carbon by steam activation. Solid State Phenomena, 302, 63-70.

Ukkakimapan, P., Sattayarut, V., Wanchaem, T., Yordsri, V., Phonyiem, M., Ichikawa, S., Obata, M., Fujishige, M., Takeuchi, K., Wongwiriyapan, W. and Endo, M., 2020. Preparation of activated carbon via acidic dehydration of durian husk for supercapacitor applications. Diamond and Related Materials, 107, DOI: 10.1016/j.diamond.2020.107906.

Yao, D., Hu, Q., Wang, D., Yang, H., Wu, C. and Wang, X., 2016. Hydrogen production from biomass gasification using biochar as a catalyst/support. Bioresource Technology, 216, 159-164.

Zhang, S., Asadullah, M., Dong, L., Tay, H.L. and Li, C.Z., 2013. An advanced biomass gasification technology with integrated catalytic hot gas cleaning. Part II: Tar reforming using char as a catalyst or as a catalyst support. Fuel, 112, 646-653.

Chang, Y.M., Tsai, W.T. and Li, M.H., 2015. Characterization of activated carbon prepared from chlorella-based algal residue. Bioresource Technology, 184, 344-348.

Foo, K.Y. and Hameed, B.H., 2011. Microwave-assisted preparation of oil palm fiber activated carbon for methylene blue adsorption. Chemical Engineering Journal, 166, 792-795.

Dulyaseree, P., Yordsri, V. and Wongwiriyapan, W., 2016. Effects of microwave and oxygen plasma treatments on capacitive characteristics of supercapacitor based on multiwalled carbon nanotubes. Japanese Journal of Applied Physics, 55(25), DOI: 10.7567/JJAP.55. 02BD05.

Dresselhaus, M.S., Dresselhaus, G., Saito, R. and Jorio, A., 2005. Raman spectroscopy of carbon nanotubes. Physics Reports, 409, 47-99.

Dresselhaus, M.S., Dresselhaus, G., Saito, R. and Jorio, A., 2010. Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Letters, 10(3), 751-758.

Smith, M.W., Dallmeyer, I., Johnson, T.J., Brauer, C.S., McEwen, J.S., Espinal, J.F. and Garcia-Perez, M., 2016. Structural analysis of char by Raman spectroscopy: Improving band assignments through computational calculations from first principles. Carbon, 100, 678-692.

Guizani, C., Haddad, K., Limousy, L. and Jeguirim, M., 2017. New insights on the structural evolution of biomass char upon pyrolysis as revealed by the Raman spectroscopy and elemental analysis. Carbon, 119, 519-521.

Faix, O., 1991. Classification of lignins from different botanical origins by FT-IR spectroscopy. Holzforschung, 45, 21-27.

Ibrahim, M., 2002. Preparation of cellulose and cellulose derivative azo compounds. Cellulose, 9, 337-349.

Sattayarut, V., Chanthad, C., Khemthong, P., Kuboon, S., Wanchaem, T., Phonyiem, M., Obata, M., Fujishige, M., Takeuchi, K., Wongwiriyapan, W., Khanchaitit, P. and Endo, M., 2019. Preparation and electrochemical performance of nitrogen-enriched activated carbon derived from silkworm pupae waste. RSC Advance, 9, 9878-9886.

Wei, T., Zhang, Q., Wei, X., Gao, Y. and Li, H., 2016. A facile and low-cost route to heteroatom doped porous carbon derived from Broussonetia papyrifera bark with excellent supercapacitance and CO2 capture performance. Scientific Reports, 6, DOI: 10.1038/srep 22646.

Chen, H., Yan-chuan, G., Wang, F., Wang, G., Qi, P. and Gua, X., 2017. An activated carbon derived from tobacco waste for use as a supercapacitor electrode material. New Carbon Materials, 32(6), 592-599.

Du, W., Zhao, Y., Zhang, Z., Du, L., Fan, X., Shen, Z., Ren, X. and Wei, C., 2019. Designing synthesis of porous biomass carbon from wheat straw and the functionalizing application in flexible, all-solid-state supercapacitors. Journal of Alloys and Compounds, 797, 1031-1040.

Peng, C., Lang, S., Xu, S. and Wang, X., 2014. Oxygen-enriched activated carbons from pomelo peel in high energy density supercapacitors. RSC Advance, 4, 54662-54667.

Karnan, M., Subramani, K., Sudhan, N., Ilayaraja, M. and Sathish, M., 2016. Aloe vera derived activated high-surface-area carbon for flexible and high-energy supercapacitors. ACS Applied Materials & Interfaces, 8, 35191-35202.

Taer E., Taslim, R., Aini, Z., Hartati, S.D. and Mustika, W.S., 2017. Activated carbon electrode from banana-peel waste for supercapacitor application. AIP Conference Proceedings, 1801, DOI: 10.1063/1.4973093.

Fasakin, O., Dangbegnon, J.K., Momodu, D.Y., Madito, M.J., Oyedotun, K.O., Eleruja, M.A. and Manyala, N., 2018. Synthesis and characterization of porous carbon derived from activated banana peels with hierarchical porosity for improved electrochemical performance. Electrochimica Acta, 262, 187-196.