Development of Chili Sauce from Pineapple and Banana Fortified with Eggshell Calcium

Main Article Content

Chowladda Teangpook*
Panita Kongsombat
Maneeploy Matum
Nunchanok Nuntachai

Abstract

Sauce is a popular condiment product. Thailand is a good source of pineapples and bananas, which are high in nutrients. Eggshell is also a source of calcium. This research developed a sauce from pineapple var. Phu Lae mixed with ripened banana var. Nam Wah and supplemented with calcium from eggshells. The suitable quantities of pineapple, banana and pineapple peel and core extract were studied based on a mixture design. The physical and chemical properties, sensory evaluation, three suitable calcium levels (0, 2, and 4%) and two pasteurization temperature levels (80-85ºC and 90-95ºC) were studied. Response surface methodology was applied and showed that all 3 components had significant effects on the sauce quality at the 0.05 level. The optimum product comprised 25.27% pineapple, 0.87% banana, 13.86% pineapple peel and core extract, 16% pickled red chili peppers, 11% pickled garlic bulbs, 26% sucrose, 2% salt, 1% vinegar, 2.12% water, and 1.88% calcium from the powdered eggshell. The product had an orange color, a pH of 4.20, and 1.61% acidity. This sauce was high in nutrients: 41.03% carbohydrate, 14.90% protein, 1.98% fat, 0.453% eggshell calcium, and 14.03 mg/kg total vitamin C. The antioxidant activity was 22.94 mg ascorbic acid/g. The optimum pasteurization temperature was 80-85ºC for 15 min. The sauce was moderately liked by panelists and has the potential to be processed into a low-cost commercial condiment.


Keywords: sauce; pineapple; banana; egg shell calcium; mixture design


*Corresponding author: E-mail: [email protected]

Article Details

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Original Research Articles

References

Marketeer, 2021. Sauce and Condiment Market: Just a Little Bit 4.7 Billion. [online] Available at: https://marketeeronline.co/archives/216406. (in Thai)

Ministry of Public Health, 2000. Notification of Ministry of Public Health (No. 201). Some Particular Kinds of Sauces. [online] Available at: https://faolex.fao.org/docs/pdf/tha160074.pdf.

Thai PBS News, 2018. Behind the Pineapple cv. Phu Lae was Oversupply. [online] Available at: https://news.thaipbs.or.th/content/272875. (in Thai)

Kusuma na Ayutaya, T., 2019. Phu Lae Pineapple, a Fruit that has Changed its Status, to the Foreign Wholesale Processing Market. [online] Available at: https://www.technologychaoban.com/marketing/article_98405. (in Thai)

Chainok, K., 2021. Pineapple: Therapeutic Fruit. [online] Available at: https://pharmacy.mahidol.ac.th/knowledge/files/0429.pdf. (in Thai)

Nanda, R.F., Bahar, R., Syukri, D., Thu, N.N.A. and Kasim, A., 2020. Review: application of bromelain enzymes in animal food products. Andalasian International Journal of Agriculture and Natural Sciences, 1(1), 33-44, DOI: 10.25077/aijans.v1.i01.33-44.2020.

Ketnawa, S. and Rawdkuen, S., 2011. Application of bromelain extract for muscle foods tenderization. Food and Nutrition Sciences, 2, 393-401.

Mahrus, H., Zulkifli, L., Rasmi, D.A.C. and Sedijani, P., 2020. Preparation and quality evaluation of sardines sauce rich in omega-3 using the combination of pineapple fruit extracts and fermentation times. Journal of Food Science and Technology, 60, 835-844, DOI: 10.1007/s13197-020-04445-y.

Promhhan, S., Rimkeeree, H., Chantrapornchai, W. and Chinputtii, S., 2007. Development of thick sauce from pineapple. Food, 37(2), 173-185.

Rat-a-pa, W., Surojanamethakul. V., Tangkanakul, P., Silayoi, B. and Wongkrajang, K., 1989. A study on the nutritional value of bananas in some ABB groups. Food, 19(4), 247-256. (in Thai)

Siriwattananon, L. and Yodsarn, S., 2021. Effect of ethylene curing on the physical properties and nutritional contents of Thai’s banana (Kluai Namwa). Proceedings of the 3rdInternational Conference on Food and Agriculture, Jember, Indonesia, November 7-8, 2020, pp. 28-32.

Boyd, J., Bruns, D., Dimarco, J., Sugg, N. and Wills, M., 1984. Relationship of potassium and magnesium concentrations in serum to cardiac arrhythmias. Clinical Chemistry, 30(5), 754-757, DOI: 10.1093/clinchem/30.5.754.

Siripanaporn, J., Boonpun, T. and Teangpook, C., 1999. Study of banana sauce processing. Food, 29(3), 167-179.

Maina, A., 2008. Development of Chili Sauce Mixed Banana Product. B.Sc. Chiang Mai University, Thailand.

Chinpakdee, K., 2003. Study of Chilli Sauce Processing from Banana Flour. B.Sc. King Mongkut’s Institute of Technology Ladkrabang, Thailand.

Domrongpokkaphan, W., 2012. Eggshell utilization technology. The Journal of Applied Science, 11(2), 75-83.

Rovenský, J., Stancíková, M., Masaryk, P., Svík, K. and Istok, R., 2003. Eggshell calcium in the prevention and treatment of osteoporosis. International Journal of Clinical Pharmacology Research, 23(2-3), 83-92.

Schaafsma, A., Pakan, I., Hofstede, G.J.H., Muskiet, F.A.J., Van Der Veer, E. and De Vries, P.J.F., 2000. Mineral, amino acid and hormonal composition of chicken eggshell powder and the evaluation of its use in human nutrition. Poultry Science, 79(12), 1833-1838.

Schaafsma, A. and Pakan, I., 1999. Effect of a chicken egg shell powder enriched dairy product on bone mineral density inpersons with osteoporosis or osteopenia. Nutrition, 15(2), DOI: 10.1016/s0899-9007(98)00164-6.

Schaafsma, A. and Beelen, G.M., 1999. Eggshell powder, a comparable or better source of calcium than purified calcium carbonate. Piglet studies. Journal of the Science of Food and Agriculture, 79(12), 1596-1600.

Hassan, N.M.M., 2015. Chicken eggshell powder as dietary calcium source in biscuits. World Journal of Dairy and Food Sciences, 10(2), 199-206, DOI: 10.5829/idosi.wjdfs.2015.10.2.1152.

Panton, C. and Suksamran, C., 2010. Preparation of Organic Calcium from Eggshell for Dietary Supplements. [online] Available at: https://pharmacy.mahidol.ac.th/th/service-research-special-abstract.php?num=41&year=2553. (in Thai)

Suan Prung Hospital, 2020. Calcium from Eggshell-Fermented Beans was Produced the First Time in the World for Alcoholic Patients. [online] Available at: https://www.youtube.com/watch?v=pxKn4nyly0w.

Chung-Wen, S., 2007. Effects of eggshell powder addition on the extrusion behavior of rice. Journal of Food Engineering, 79(2), 607-612, DOI: 10.1016/j.jfoodeng.2006.02.019.

Heaney, R.P., Recker, R.R. and Weaver, C.M., 1990. Absorbability of calcium sources: the limited role of solubility. Calcified Tissue International, 46, 300-304, DOI: 10.1007/BF02563819.

Barbara, D., Marta, J., Beata, S. and Florian, R., 2016. Use of eggshells as a raw material for production of calcium preparations. Czech Journal of Food Sciences, 34(4), 313-317, DOI: 10.17221/59/2016-CJFS.

Tae, H.K., 2017. Functional Method of Producing Soy Sauce and Vinegar with Egg Shell Calcium. Korea, Pat. KR20170127712 (A).

Daengprok, W. and Supavititpatana, P., 2007. Eggshell Calcium-Fortified Corn Milk Yoghurt. [online] Available at: https://tarr.arda.or.th/preview/item/Zrv164bMyLjbvFo0P5Wo0.

Changpuak, A. and Garnjanagoonchorn, W., 2007. Preparation and partial characterization of eggshell calcium chloride. International Journal of Food Properties, 10(3), 497-503, DOI: 10.1080/10942910600919484.

Thakur, R.J., Shaikh, H., Gat, Y. and Waghmare, R.B., 2019. Effect of calcium chloride extracted from eggshell in maintaining quality of selected fresh-cut fruits. International Journal of Recycling of Organic Waste in Agriculture, 8, 27-36, DOI: 10.1007/s40093-019-0260-z.

Nunpakdee, I. and Charuchinda, A., 2020. Processing of Calcium from Eggshell. Thailand, Pat. 1446.

Boonchom, B., 2017. Process for Producing Calcium Lactate from Shells and/or Eggshells and Products Obtained from Such Processes. Thailand, Request number 1701001862.

Boonchom, B., 2017. Process for Producing Calcium Acetate from Shells and/or Eggshells and Products Obtained from Such Processes. Thailand, Request number 1701001861.

Boonchom, B., 2018. Process for Producing Calcium Citrate from Shells and/or Egg Shells and Products Obtained from Such Processes. Thailand, Request number 1801002669.

Xiao, Z., Xin, G. and Deyu, Y., 2008. Method for Producing Calcium Acetate with Egg Shell. China. Pat. CN101172942A.

Cornell, J., 2002. Experiments with Mixtures: Designs, Models, and the Analysis of Mixture Data. New York: John Wiley and Sons, Inc.

Khuri, A.I. and Cornell, J.A., 1987. Response Surfaces: Designs and Analyses. New York: Marcel Dekker, Inc.

Hartmann, B.G. and Hillig, F., 1930. Determination of citric acid in fruits and fruit products. Journal of Association of Official Agricultural Chemists, 3(1), 99-103, DOI: 10.1093/jaoac/13.1.99.

AOAC, 2000. Official Methods of Analysis. Washington DC: Association of Official Analytical Chemists.

Latimer, G.W., 2019. Official Methods of Analysis of the AOAC International. 21st ed. Washington DC: Association of Official Analytical Chemists.

Kim, D.O., Lee, K.W., Lee, H.J. and Lee, C.Y., 2002. Vitamin C equivalent antioxidant capacity (VCEAC) of phenolic phytochemicals. Journal of Agricultural and Food Chemistry, 50(13), 3713-3717, DOI: 10.1021/jf020071c.

Nakano, T., Ikawa, N.I. and Ozimek, L., 2003. Chemical composition of chicken eggshell and shell membranes. Journal of Poultry Science, 82(3), 510-514, DOI: 10.1093/ps/82.3.510.

Nys, Y., Gautron, J., Garcia-Ruiz, J.M. and Hincke, M.T., 2004. Avian eggshell mineralization: biochemical and functional characterization of matrix proteins. Comptes Rendus Palevol, 3, 549-562, DOI: 10.1016/j.crpv.2004.08.002.

Pikul, D., Garnjanagoonchorn, W. and Thanachasai, S., 2014. The development of eggshell membrane hydrolysate. Proceedings of the 52nd Kasetsart University Annual Conference, Bangkok, Thailand, February 4-7, 2014, pp. 82-89.

Lund, M.N. and Ray, C.A., 2017. Control of maillard reactions in foods: Strategies and chemical mechanisms. Journal of Agricultural and Food Chemistry, 65, 4537-4552, DOI: 10.1021/acs.jafc.7b00882.

Ramesh, M.N., 2020. Pasteurization and food preservation. In: M.S. Ramesh, ed. Handbook of Food Preservation. 2nd ed. Bota Raton: CRC Press, pp. 571-582.

National Center for Biotechnology Information, 2021. Calcium Acetate. [online] Available at: https://pubchem.ncbi.nlm.nih.gov/compound/Calcium-acetate.

Beto, J.A., 2015. The role of calcium in human aging. Clinical Nutrition Research, 4(1), 1-8, DOI: 10.7762/cnr.2015.4.1.1.

U.S. Department of Agriculture, 2022. Pineapple, Raw. [online] Available at: https://fdc.nal. usda.gov/fdc-app.html#/food-details/2346398/nutrients.

Du, J., Cullen, J.J. and Buettner G.R., 2012. Ascorbic acid: Chemistry, biology and the treatment of cancer. Biochimica et Biophysica Acta, 1826, 443-457, DOI: 10.1016/j.bbcan.2012.06.003.

Medicinal Plants Innovation Center of Mae Fah Luang University, 2021. Enzyme Bioactivity Test. [online] Available at: https://mpic.mfu.ac.th/mpic-academicservices/mpic-testingservice/mpic-standardizedherb.html. (in Thai)

Sharma, O.P. and Bhat, T.K., 2009. DPPH antioxidant assay revisited. Food Chemistry, 113, 1202-1205, DOI: 10.1016/j.foodchem.2008.08.008.

Xie, J. and Schaich, K.M., 2014. Re-evaluation of the 2,2-Diphenyl-1-picrylhydrazyl free radical (DPPH) assay for antioxidant activity. Journal of Agricultural and Food Chemistry, 62(19), 4251-4260, DOI: 10.1021/jf500180u.

Pineli, L.D.L.D.O., Aguiar, L.A.D., Fiusa, A., Botelho, R.B.D.A., Zandonadi, R.P. and Melo, L., 2016. Sensory impact of lowering sugar content in orange nectars to design healthier, low-sugar industrialized beverages. Appetite, 96, 239-244, DOI: 10.1016/j.appet.2015.09.028.