Enhancing Latex Compounds and Vulcanized Rubber Properties with Silver Nanoparticles

Main Article Content

Jutatip Artchomphoo
Suwat Rattanapan
Irfun Masaesa-i
Weerasak Taengphan
Diew Saijun

Abstract

The production process of latex products requires the preparation of latex compounds by mixing latex with chemicals in a dispersion state. This experiment investigated the influence of added zinc oxide and silver nanoparticles on the properties of latex compounds and vulcanized rubber. It was found that increasing the amount of zinc oxide in the rubber compound resulted in a rise in the viscosity of the latex over the storage period. Increasing the zinc oxide content also led to a higher degree of crosslink noticed by a faster chloroform number determination of the vulcanization level and the opposite effect on the swell value of the rubber film with reduced swelling. The amount of 2.0 phr of ZnO as an activator gave the highest value of the tensile strength. The increasing amount of silver nanoparticles caused a decrease in the viscosity and exhibited a slower chloroform number with a decrease in the swelling of the rubber film. The amount of silver nanoparticles in the study period (0.0010-0.0022 phr) had little effect on mechanical properties but a significant effect on antibacterial activity. The 0.0010 phr of silver nanoparticles showed sufficient potential in inhibiting Staphylococcus aureus and Escherichia coli.

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Original Research Articles

References

Suksup, R., Imkaew, C. and Smitthipong, W., 2017. Cream concentrated latex for foam rubber products. IOP Conference Series: Material Science and Engineering, 272, https://doi.org/10.1088/1757-899X/272/1/012025.

Reis, G.O., Menut, P., Bonfils, F., Vaysse, L., Hemer, Y. and Sanchez, C. 2015. Acid-induced aggregation and gelation of natural rubber latex particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 482, 9-17, http://doi.org/10.1016/j.colsurfa.2015.04.015.

Yu, H., Wang, Q., Li, J., Liu, Y., He, D. and Gao, X., 2017. Effect of lipids on the stability of natural rubber latex and tensile properties of its films. Journal of Rubber Research, 20(4), 213-222.

Salomez, M., Subileau, M., Intapun, J., Bonfils, F., Sainte- Beuve, J., Vaysse, L. and Dubreucq, E., 2014. Micro-organisms in latex and natural rubber coagula of Hevea brasiliensis and their impact on rubber composition, structure and properties. Journal of Applied Microbiology, 117, 921-929.

Santipanusopon, S. and Riyajan, S.-A., 2009. Effect of field natural rubber latex with different ammonia contents and storage period on physical properties of latex concentrate, stability of skim latex and dipped film. Physics Procedia, 2, 127-134, https://doi.org/10.1016/j.phpro.2009.06.020.

Khamput, P. and Suweero, K., 2011. Properties of mortar mixing with medium ammonia concentrated Latex. Energy Procedia, 9, 559-567.

Sasidharan, K.K., Josept, R., Palaty, S., Gopalakrishnan, K.S., Rajammal, G. and Pillai, P.V., 2005. Effect of the vulcanization time and storage on the stability and physical properties of sulfur-prevulcanized natural rubber latex. Journal of Applied Polymer Science, 97, 1804-1811, https://doi.org/10.1002/app.21918.

Sirisomboon, P. and Lim, C.H., 2019. Rapid evaluation of the properties of natural rubber latex and its products using near-Infrared spectroscopy. In: A. Sand and E.G. Zaki, eds. Organic Polymers. London: IntechOpen, https://doi.org/10.5772/intechopen.8549.

Phomrak, S., Nimpaiboon, A., Newby, B.Z. and Phisalaphong, M., 2020. Natural rubber latex foam reinforced with micro and nanofibrillated cellulose via Dunlop method. Polymers, 12, https://doi.org/10.3390/polym12091959.

Pornprasit, P., Pechurai, W., Chiangraeng, N., Randorn, C., Chandet, N., Mungkornasawakul, P. and Nimmanpipug, P., 2018. Nanomodified ZnO in natural rubber and its effects on curing characteristics and mechanical properties. Chiang Mai Journal of Science, 45(5), 2195-2200.

Wijnhoven, S.W.P., Peijnenburg, W.J.G.M., Herberts, C.A., Hagens, W.I., Oomen, A.G., Heugens, E.H.W., Roszek, B., Bisschops, J., Gosens, I., De Meent, D.V., Dekkers, S., De Jong, W.H., van Zijverden, M., Sips, A.J.A.M. and Geertsma., R.E., 2009. Nano- silver – a review of available data and knowledge gaps in human and environmental risk assessment, Nanotoxicology, 3(2), 109-138, https://doi.org/10.1080/17435390902725914.

Kornkai, K. and Phatharamanon, R., 2017. Plant extract synthesized silver nanoparticles and their antimicrobial activity. KKU Science Journal, 45(1), 34-52. (in Thai)

Keawkong, N., Sripanom, L., Jea-U-bong, J. and Thiphoo, S., 2014. Synthesis and characterization of physical and antimicrobial properties of silver nanoparticles synthesis based on chemical reduction method. Science and Technology RMUTT Journal, 4(2), 1-10. (in Thai)

Crisan, C.M., Mocan, T., Manolea, M., Lasca, L.L., Tăbăran, F.-A. and Mocan, L., 2021. Review on silver nanoparticles as a novel class of antibacterial solutions. Applied Science, 11(3), https://doi.org/10.3390/app11031120.

Thanasuwannakul, N., Buntum, T. and Suwantong, O., 2023. Preparation and characterization of porous natural rubber loaded with silver nanoparticles. Current Applied Science and Technology, 23(3), https://doi.org/10.55003/cast.2022.03.23.008.

Rathnayake, W.G.I.U., Ismail, H., Baharin, A., Darsanasiri, A.G.N.D. and Rajapakse, S., 2012. Synthesis and characterization of nano silver based natural rubber latex foam for imparting antibacterial and anti-fungal properties. Polymer Testing, 31, 586-592, https://doi.org/10.1016/j.polymertesting.2012.01.010.

Zhang, Y., Xue, X., Zhang, Z., Liu,Y. and Li, G., 2014. Morphology and antibacterial properties of natural rubber composites based on biosynthesized nanosilver. Journal of Applied Polymer Science, 131(18), https://doi.org/0.1002/app.40746.

Sarih, N.M., Gwee, K., Maher, S. and Rashid, A.A., 2002. Natural rubber (NR) latex films with antimicrobial properties for stethoscope diaphragm covers. Materials, 15, https://doi.org/10.3390/ma15103433.

Krishnamoothy, A., Varghese, S. and Kurian, T., 2015. Effect of micro and nano zinc oxide on the properties of pre-vulcanized natural rubber latex films. Progress in Rubber, Plastics and Recycling Technology, 31(3), 145-156, http://doi:10.1177/147776061503100301.

Chukwu, M.N., Ekhator, I. and Ekebafe, L.O., 2019. Effect of zinc oxide level as activator on the mechanical properties of natural rubber composite. Nigerian Journal of Technology, 38(3), 675-679, https://doi.org/10.4314/njt.v38i3.19.

Ruslimie, C.A., Norhanifah M.Y., Fatimah Rubaizah, M.R., Asrul M. and Rubaizah, M.R.F., 2015. Effect of prevulcanisation time on the latex particles, surface morphology and strength of epoxidized natural rubber films. 3rd International Conference on Chemical, Agricultural and Medical Sciences (CAMS-2015), Singapore, December 10-11, 2015, pp. 64-69.

Vinod, V.S., Varghese, S., Alex, R. and Kuriakose, B. 2001. Effect of aluminum powder on filled natural rubber composites. Rubber Chemistry and Technology, 74(2), 236-248. https://doi.org/10.5254/1.3544947.

Doma, A.S., El-Khatib, A.E., Abu-Rayan, A.E., Wazeer, W. and Abbas, M.I., 2021. A study on some physical properties of conductive Pb/NR composites. Journal of Rubber Research, 24, 807-817, https://doi.org/10.1007/s42464-021-00137-0.

Barrera, C.S. and Cornish, K., 2017. Processing and mechanical properties of natural rubber/waste-derived nano filler composites compared to macro and micro filler composites. Industrial Crops and Products, 107, 217-231, https://doi.org/10.1016/j.indcrop.2017.05.045.

Naphon, P., Wiriyasart, S. and Naphon, N., 2020. Thermal, mechanical, and electrical properties of rubber latex with TiO2 nanoparticles. Composites Communications, 22, https://doi.org/10.1016/j.coco.2020.100449.

Cabrera, F.C., Agostini, D.L.S., dos Santos, R.J., Teixeira, S.R., Rodríguez-Pérez, M.A. and Job, A.E., 2013. Characterization of natural rubber/gold nanoparticles SERS-active substrate. Journal of Applied Polymer Science, 130(1), 186-192, https://doi.org/10.1002/app.39153.