From Waste to Energy: Optimizing Briquette Properties from Sago Palm Residue with Glycerin Binder

Main Article Content

Patcharee Intanoo
Pitchayapon Klabklay

Abstract

This research investigated the effects of carbonization temperature (from 300°C to 500°C) and glycerin content (from 0.00% to 60.00% by weight) on the physical and thermal properties of briquette produced from sago palm residue. The results revealed that increasing both the carbonization temperature and glycerin content enhanced the physical properties of the briquettes—particularly the shatter index (%shatter index) and durability (%Dr)—mainly due to greater densification. This enhancement led to superior briquette because glycerin helped to increase bulk density and reduce void spaces between particles. Both glycerin content and carbonization temperature had positive effects on thermal properties. Briquette produced by carbonizing sago palm residue at 400°C with 60.00% glycerin exhibited the best thermal characteristics, with the highest heating value and energy density of 22.15 MJ/kg and 12,847 MJ/m3, respectively. This was because the proportions of combustible components—fixed carbon (FC) and volatile matter (VM)—were 1.04 times higher than those of briquettes produced by carbonizing the sago palm residue at 300°C and 500°C with 60.00% glycerin. Higher combustible components resulted in greater energy output, which was reflected in the lower fuel consumption needed when boiling 20.00 mL of water. The consumption of briquettes produced by carbonizing sago palm residue at 400°C was 33.90% and 19.95% less than briquettes produced by carbonizing sago palm residue at 300°C and 500°C, respectively (12.83 g for 300°C). In accordance with the maximum energy-mass co-benefit index (EMCI) of 15.52, the optimum carbonization temperature for producing effective briquettes from sago palm residue was 400°C.

Article Details

How to Cite
Intanoo, P., & Klabklay, P. (2026). From Waste to Energy: Optimizing Briquette Properties from Sago Palm Residue with Glycerin Binder. CURRENT APPLIED SCIENCE AND TECHNOLOGY, e0269237. https://doi.org/10.55003/cast.2026.269237
Section
Original Research Articles
Author Biography

Patcharee Intanoo, Department of Industrial Chemistry Innovation, Faculty of Science, Maejo University Nonghan, Sansai, Chiang Mai, Thailand

พัชรี อินธนู

References

Ali, F., Dawood, A., Hussain, A., Alnasir, M. H., Khan, M. A., Butt, T. M., Janjua, N. K., & Hamid, A. (2024). Fueling the future: biomass applications for green and sustainable energy. Discover Sustainability, 5(1), Article 156. https://doi.org/10.1007/s43621-024-00309-z

Altıkat, A., Alma, M. H., Altıkat, A., Bilgili, M. E., & Altıkat, S. (2024). A comprehensive study of biochar yield and quality concerning pyrolysis conditions: a multifaceted approach. Sustainability, 16(2), Article 937. https://doi.org/10.3390/su16020937

Amin, N., Sabli, N., Izhar, S., & Yoshida, H. (2019). Sago wastes and its applications. Science and Technology, 27(4), 1841-1862.

Asavatesanupap, C., & Malee, S. (2010). A feasibility study on production of solid fuel from glycerol and agricultural wastes.

International Transaction Journal of Engineering, Management, and Applied Sciences and Technologies, 1(1), 43-51.

Awg-Adeni, D. S., Abd-Aziz, S., Bujang, K., & Hassan, M. A. (2009). Bioconversion of sago residue into value added products. African Journal of Biotechnology, 9(14), 2016-2021.

Bielecki, M., & Zubkova, V. (2022). Analysis of interactions occurring during the pyrolysis of lignocellulosic biomass. Molecules, 28(2), Article 506. https://doi.org/10.3390/ molecules28020506

Campbell, M., Treble, P. C., McDonough, L. K., Naeher, S. A., Baker, A., Grierson, P. F. Wong, H., & Andersen, M. S. (2024). Combustion completeness and sample location determine wildfire ash leachate chemistry. Geochemistry, Geophysics, Geosystems, 25, Article e2024GC011470. https://doi.org/10.1029/2024GC011470

Elkhalifa, S., Parthasarathy, P., Mackey, H. R., Al Ansari, T., Elhassan, O., Mansour, S. & McKay, G. (2022). Biochar development from thermal TGA studies of individual food waste vegetables and their blended systems. Biomass Conversion and Biorefinery, 15, 29965-29982. https://doi.org/10.1007/s13399-022-02441-0

Elsisi, S. F., Omar, M. N., Azam, M. M., Eissa, A. H. A., & Gomaa, E. M. (2025). Effect of pyrolysis process on the properties of briquettes produced from different particle size peanut shells and grape pruning residues. Biomass and Bioenergy, 193, Article 107532. https://doi.org/10.1016/j.biombioe.2024.107532

Fetriyuna, F., Letsoin, S. M. A., Jati, I. R. A. P., & Purwestri, R. C. (2024). Potential of underutilized sago for bioenergy uses. International Journal on Advanced Science, Engineering and Information Technology, 14(1), 144-150. https://doi.org/10.18517/ijaseit.14.1.19202

Glalah, M., Antwi-Boasiako, C., & Adu-Gyamfi, D. (2024). Binder-type effect on the physico-mechanical, combustion and emission properties of Alstonia boonei De Wild. sawdust and Theobroma cacao L. pod biochar briquettes for energy applications. PLoS ONE, 19(7), Article e0306827. https://doi.org/10.1371/journal.pone.0306827

Guo, J., Zhang, Y., Fang, J., Ma, Z., Li, C., Yan, M., Qiao, N., Liu, Y., & Bian, M. (2024). Reduction and reuse of forestry and agricultural bio-waste through innovative green utilization approaches: a review. Forests, 15(8), Article 1372. https://doi.org/10.3390/f15081372

Hakim, L., Iswanto, A. H., Lubis, Y. S., Wirawan, A. J., Batubara, Kim, N. H., Antov, P., Rogozinski, T., Hua, L. S., Chen, L. W., Selvasembian, R., Jayusman, & Sutiawan, J. (2025). Charcoal briquette manufactured from Indonesian sugar palm bunches (Arenga longipes Mogea) as biomass-based new renewable energy. Journal of Renewable Materials, 13(3), 637-650. https://doi.org/10.32604/jrm.2025.056365

Ibitoye, S. E., Mahamood, R. M., Jen, T. C., & Akinlabi, E. T. (2022). Combustion, physical, and mechanical characterization of composites fuel briquettes from carbonized banana stalk and corncob. International Journal of Renewable Energy Development, 11(2), 435-447. https://doi.org/10.14710/ijred.2022.41290

Ilari, A., Duca, D., Boakye-Yiadom, K. A., & Gasperini, T. (2022). Carbon footprint and feedstock quality of a real biomass power plant fed with forestry and agricultural residues. Resources,11, Article 7. https://doi.org/10.3390/resources11020007

Imran, A. I., Siregar, J. P., Palanisamy, S., Cionita, T., Fitriyana, D. F., Dewi, R., Laksmono, J. A., Roseno, S., Mausam, K., Sankar, S. L., Massoud, E. E. S., & Al-Farraj, A. A. (2025). Exploring the potential of sago residues for eco-fraindly construction materials. BioResources, 20(3), 8175-8208. https://doi.org/10.15376/biores.20.3.Imran

International Energy Agency. (2023). World energy outlook 2023. https://www.iea.org/reports/world-energy-outlook-2023/

International Energy Agency. (2025). Global energy review 2025 https://www.iea.org/reports/global-energy-review-2025/

Jariyapong, M., Roongtawanreongsri, S., & Somboonsuke, B. (2023). Estimating the economic value of carbon sequestration by sago palm (Metroxylon sagu Rottb.) in Thailand. International Journal of Design and Nature and Ecodynamics, 18(5), 1159-1167. https://doi.org/10.18280/ijdne.180517

Jayasuriya, W. J., Mulky, T. C., & Niemeyer, K. E. (2022). Smoldering combustion in cellulose and hemicellulose mixtures: Examining the roles of density, fuel composition, oxygen concentration, and moisture content. Combustion Theory and Modelling, 26(5), 831-855. https://doi.org/10.1080/13647830.2022.2071170

Kabas, Ö., Ünal, I., Sözer, S., Selvi, K. C., & Ungureanu, N. (2022). Quality assessment of biofuel briquettes obtained from greenhouse waste using a mobile prototype briquetting machine with PTO drive. Energies, 15, Article 8371. https://doi.org/10.3390/en15228371

Kaliyan, N., & Morey, R. V. (2009). Factors affecting strength and durability of densified biomass products. Biomass and Bioenergy, 33(3), 337-359. https://doi.org/10.1016/j.biombioe.2008.08.005

Kebede, T., Berhe, D. T., & Zergaw, Y. (2022). Combustion characteristics of briquette fuel produced from biomass residues and binding materials. Journal of Energy, 12, 1-10. https://doi.org/10.1155/2022/4222205

Kpalo. S. Y., Zainuddin, M. F., Manaf, L. A., & and Roslan, A. M. (2020). A review of technical and economic aspects of biomass briquetting. Sustainability, 12, Article 4609. https://doi.org/10.3390/su12114609

Liang, X., Li, Z., Dong, H., & Ye, G. (2024). A review on the characteristics of wood biomass fly ash and their influences on the valorization in cementitious materials. Journal of Building Engineering, 97, Article 110927. https://doi.org/10.1016/j.jobe.2024.110927

Lin, B. J., Sliveira, E. A., Colin, B., Chen, W. H., Pétrissans, A., Rousset, P., & Pétrissans, M. (2019). Prediction of higher heating values (HHVs) and energy yield during torrefaction via kinetics. Energy Procedia, 158, 111-116. https://doi.org/10.1016/j.egypro.2019.01.054

Liu, X., Li, D., Yang, J., & Yuan, L. (2022). Kinetic mechanisms and emissions investigation of torrefied pine sawdust utilized as solid fuel by isothermal and non-isothermal experiments. Materials, 15(23), Article 8650. https://doi.org/10.3390/ma15238650

Lohani, T. K., Seboka, Y., Biliso, W. B., & Reza, S. (2024). An assessment of bamboo charcoal briquettes derived from the two main bamboo species in Ethiopia. Advances in Bamboo Science, 9, Article 100106. https://doi.org/10.1016/j.bamboo.2024.100106

Lv, Y. (2023). Transitioning to sustainable energy: opportunities, challenges, and the potential of blockchain technology. Frontiers in Energy Research, 11, Article 1258044. https://doi.org/10.3389/fenrg.2023.1258044

Ma, Z., Ye, J., Zhao, C., & Zhang, Q. (2015). Gasification of rice husk in a downdraft gasifier: The effect of equivalence ratio on the gasification performance, properties, and utilization analysis of byproducts of char and tar. BioResources, 10(2), 2888-2902. https://doi.org/10.15376/biores.10.2.2888-2902

Mehmood, K., Bao, Y., Saifullah, Bibi, S., Dahlawi, S., Yaseen, M., Abrar, M. M., Srivastava, P., Fahad, S., & Faraj, T. K. (2022). Contributions of open biomass burning and cropstraw burning to air quality: current research paradigm and future outlooks. Frontiers in Environmental Science, 10, Article 852492. https://doi.org /10.3389/fenvs.2022.852492

Menkoed, C., Prakobkasikorn, P., & Kumboon, P. (2017). Fuel briquette produced from brick manufactory waste. [unpublished Bachelor thesis]. Naresuan University.

Moklis, M. H., Cheng, S., & Cross, J. D. (2023). Current and future trends for crude glycerol upgrading to high value-added products. Sustainability, 15, Article 2979. https://doi.org/10.3390/su15042979

Moshawih S., Kong, J. P. T., Goh, B. H., Renganathan, E., Goh, H. P., Goh, K. W., & Ming, L. C. (2025). Exploring the nutritional, cultural, and industrial significance of Metroxylon Sagu. Discover Food, 5, Article 337. https://doi.org/10.1007/s44187-025-00638-6

Mueanmas, C., & Rakmak, N. (2024). Fuel properties improvement of palm kernel shell with torrefaction process by using screw conveyor reactor. Burapha Science Journal, 29(1), 245-265.

Ngene, G. I., Bouesso, B., Martínez, M. G., & Nzihou, A. (2024). A review on biochar briquetting: Common practices and recommendations to enhance mechanical properties and environmental performances. Journal of Cleaner Production, 469, Article 143193. https://doi.org/10.1016/j.jclepro.2024.143193

Obi, O. F., Pecenka, R., & Clifford, M. J. (2022). A review of biomass briquette binders and quality parameters. Energies, 15(7), Article 2426. https://doi.org/10.3390/en15072426

Owino, C. A., Lubwama, M., Yiga, V. A., Were, F., Bongomin, O., & Serugunda, J. (2024). Mechanical and thermal properties of composite carbonized briquettes developed from cassava (Manihot esculenta) rhizomes and groundnut (Arachis hypogea L.) stalks with jackfruit (Artocarpus heterophyllus) waste as binder. Discover Applied Sciences, 6, Article 428. https://doi.org/10.1007/s42452-024-06123-6

Pinho, R., & Borges, A. D. S. (2025). Comprehensive evaluation of combustion performance and emissions from commercial pellets in small-scale boilers. Energies, 18, Article 3545. https://doi.org/10.3390/en18133545

Portilho, G. R., Castro, V. R., Carneiro, A. C. O., Zanuncio, J. C., 2, Zanuncio, A. J. V., Surdi, P. G., Gominho, J., & Araújo, S. O. (2020). Potential of briquette produced with torrefied agroforestry biomass to generate energy. Forests, 11(12), Article 1272. https://doi.org/10.3390/f11121272

Qian, W., Kuihua, H., Jie, G., Hui, L., & Chunmei, L. (2017). The pyrolysis of biomass briquettes: Effect of pyrolysis temperature and phosphorus additives on the quality and combustion of bio-char briquettes. Fuel, 199, 488-496. https://doi.org/10.1016/j.fuel.2017.03.011

Sahupala, P., & Kakerissa, Y. (2022). The utilization of sago due waste as an alternative fuel. Engineering and Technology Journal, 7(9), 1504-1514. https://doi.org/10.47191/etj/v7i9.11

Sarker, T. R., Nanda, S., Dalai, A. K. & Meda, V. (2021). A review of torrefaction technology for upgrading lignocellulosic biomass to solid biofuels. Bioenergy Research, 14, 645-669. https://doi.org/10.1007/s12155-020-10236-2

Sarker, T. R., Nanda, S., Meda, V., & Dalai, A. K. (2022). Densification of waste biomass for manufacturing solid biofuel pellets: a review. Environmental Chemistry Letters, 21, 231-264. https://doi.org/10.1007/s10311-022-01510-0

SDA. (1990). Glycerine: an overview. The Soap and Detergent Association.

Sengar, S. H., Mohod, A., Khandetod, Y., & Patil, S. (2012). Performance of briquetting machine for briquette fuel. International Journal of Energy and Engineering, 2(1), 28-34. https://doi.org/10.5923/j.ijee.20120201.05

Singhal, R. S., Kennedy, J. F., Gopalakrishnan, S. M., Kaczmarek, A., Knill, C.J., & Akmar, P. F. (2008). Industrial production, processing, and utilization of sago palm-derived products. Carbohydrate Polymers, 72, 1-20. https://doi.org/10.1016/j.carbpol.2007.07.043

Slezak, R., Unyay, H., Szufa, S., & Ledakowicz, S. (2023). An extensive review and comparison of modern biomass reactors torrefaction vs. biomass pyrolizers—part 2. Energies, 16, Article 2212. https://doi.org/10.3390/en16052212

Soliño, M., Prada, A., & Vázquez, M.X. (2009). Green electricity externalities: Forest biomass in an Atlantic European Region. Biomass and Bioenergy, 33(3), 407-414. https://doi.org/10.1016/j.biombioe.2008.08.017

Susanto, B., Tosuli, Y. T., Adnan, Cahyadi, Nami, H., Surjosatyo, A., Alandro, D., Nugroho, A. D., Rashyid, M. I., & Muflikhun, M. A. (2024). Characterization of sago tree parts from Sentani, Papua, Indonesia for biomass energy utilization. Heliyon, 10(1), Article e23993. https://doi.org/10.1016/j.heliyon.2024.e23993

Thailand Greenhouse Gas Management Organization. (2022, July). Thai National LCI Database.https://thaicarbonlabel.tgo.or.th/index.php?lang=TH&mod=Y0hKdlpIVmpkSE5mWlcxcGMzTnBiMjQ9

Tufail, F., Saquib, M., Singh, S., Tiwari, J., Dixit, P., Singh, J., & Singh, J. (2018). A practical green approach to diversified spirochromene/spiropyran scaffolds via a glucosewater synergy driven organocatalytic system. New Journal of Chemistry, 42(21), 17279-17290. https://doi.org/10.1039/C8NJ03028F

Tumuluru, J. S., Ghiasi, B., Soelberg, N. R., & Sokhansanj, S. (2021). Biomass torrefaction process, product properties, reactor types, and moving bed reactor design concepts. Frontiers in Energy Research, 9, Article 728140. https://doi.org/10.3389/fenrg.2021.728140

Wang, K., Remón, J., Jiang, Z., & Ding, W. (2024). Recent advances in the preparation and application of biochar derived from lignocellulosic biomass: a mini review. Polymers, 16(6), Article 851. https://doi.org/10.3390/polym16060851

Wang, H., Li, H., Lee, C. K., Nanyan, N. S. M., & Tay, G. S. (2024). A systematic review on utilization of biodiesel-derived crude glycerol in sustainable polymers preparation. International Journal of Biological Macromolecules, 261, Article 129536. https://doi.org/10.1016/j.ijbiomac.2024.129536

Wang, Q., Han, K., Gao, J., Li, H., & Lu, C. (2017). The pyrolysis of biomass briquettes: Effect of pyrolysis temperature and phosphorus additives on the quality and combustion of bio-char briquettes. Fuel, 199, 488-496. https://doi.org/10.1016/j.fuel.2017.03.011

Wijitkosum, S. (2023). Influence of pyrolysis temperature and time on biochar properties and its potential for climate change mitigation. Journal of Human, Earth and Future, 4(4), 472-485. https://doi.org/10.28991/HEF-2023-04-04-07

Winata, A. A., Ihwan, M. Y., Irawan, C., Wijayanti, H., Putra, M. D., & Muttaqii, M. A. (2025). Potential production and characterization of charcoal-based bio-briquettes from Ulin wood waste as an alternative sustainable energy resource. Journal of Chemical Technology and Metallurgy, 60(4), 595-608. https://doi.org/10.59957/jctm.v60.i4.2025.7

Yang, W., Feng, S., Xu, Y., Zhu, Y., Xin, S., Hu, W., Li, P., Liu, H., & Yang, H. (2025). Effect of densification pretreatment on combustion and particulate matter emission characteristics of agricultural biomass. Royal Society Open Science, 12, Article 240848. https://doi.org/10.1098/rsos.240848

Yirijor, J., Adazabra, A. N., & McBagonluri, F. (2023). Fabrication and characterization of charcoal briquettes fuel from a blend of coconut husk and corncob. Journal of Energy Research and Reviews, 13(1), 14-24. https://doi.org/10.9734/JENRR/2023/v13i1254

Zhai, Y., Wang, T., Zhu, Y., Peng, C., Wang, B., Li, X., Li, C., & Zeng, G. (2018). Production of fuel pellets via hydrothermal carbonization of food waste using molasses as a binder. Waste Management, 77, 185-194. https://doi.org/10.1016/j.wasman.2018.05.022