Determination of Oxalic Acid in Thai Local Vegetables by Precipitation of Sodium Oxalate
Keywords:
Oxalic Acid, Thai Local Vegetables, Sodium Oxalate PrecipitationAbstract
This study was aimed to determine, analyze and compare the oxalic acid content in 9 types of Thai local vegetables, focusing only on the edible parts, which were dried (dry matter: DM). The study employed the sodium oxalate (Na2C2O4) precipitation method and titration to determine the amount of oxalic acid (C2H2O4: HOOCCOOH), with the results expressed in mg/100g DM. It was found that the oxalic acid content in the 9 vegetable samples ranged from 2138.21 ± 15.79 mg/100g DM to 140.67 ± 20.00 mg/100g DM. The three vegetables with the highest oxalic acid content were Basella alba L. (2138.21 ± 15.79 mg/100g DM), Amaranthus viridis L. (2081.94 ± 2.70 mg/100g DM), and Commelina benghalensis L. (1688.06 ± 0.00 mg/100g DM). The study showed that the sodium oxalate precipitation method is effective for detecting oxalic acid content. However, the findings should be confirmed using more accurate and precise methods, and further studies should explore oxalic acid content in other Thai local vegetables.
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References
Chinpraditsuk S, Chatkrailert A. Oxalate Nephropathy. ournal of the Nephrology Society of Thailand. 2023;29(2):107–115.
Promdang S, Benjawan S, Doung-ngern U, Sukkhaeng S. Oxalate content and antioxidant properties in 12 genotypes of amaranth. KHON KAEN AGR. J. 2020;48(1):1065–1072.
Kengkat Y, Jongthonglang P, Phromprasit P. Examination of Calcium Oxalate Crystals in Local Vegetables from Ban Mai Subdistrict, Khon Buri District, Nakhon Ratchasima Province. Science and Technology Research Journal Nakhon Ratchasima Rajabhat University. July–December 2022;7(2):75–82.
Chanapa P. The Risk Factors of Kidney Stones Focusing on Calcium and Oxalate. Songkla Med J. Nov-Dec 2011;29(6): 299-308.
Kusuma D.S.,et al. Evaluation of extraction parameters for total oxalate determination in spinach using design of experiment analysis. Journal of Food Composition and Analysis. 2016;51:9-14.
Nakorn B. Determination of Oxalic acid in Thai vegetables by Precipitation of Calcium Oxalate. Ubonratchatani: Faculty of Science and Technology, Ubonratchatani Rajabhat University. 2003.
Boonmalai A, Sangchaimongkonlap K, Bhudsri K. Determination of oxalate in vegetable samples using a low cost electrode by potentiometric microtitration method. Phranakhon Rajabhat Research Journal (Science and Technology). July - December 2019;14(2): 148-160.
Fatoki O S. Ambient temperature acid extraction method for the determination of oxalic acid contents of vegetables. Journal of Agricultural and Food Chemistry. February 1991;39(2):293-295.


