Synthesis of Flower-like Kesterite Cu2ZnSnS4 Nanostructures using Different Sulfur Sources and Applications
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Abstract
In this study, surfactant-free quaternary copper zinc tin sulfide (CZTS) nanostructures were successfully synthesized using two different chalcogen/sulfur precursors by hydrothermal method. The effects of different sulfur sources such as thiourea (TU) and thioacetamide (TAA) on the structural, functional, and morphological properties were investigated. XRD analysis revealed that pure phase of kesterite CZTS nanostructures were found at higher concentrations of thiourea. Raman studies proved the existence of the phase purity of CZTS at TU-10. Morphological investigation of CZTS nanostructures showed different morphologies such as spherical-like, rose flower-like, and plate-like structures, at different concentrations of thiourea. Structural and morphological studies confirmed that the formation of single-phase CZTS nanostructures was possible at higher concentrations of TU. HRTEM analysis of CZTS TU-10 confirmed that the lattice value of 0.31 nm corresponded to the (112) plane and the SAED pattern exhibited a polycrystalline nature. EDS mapping of CZTS nanostructures confirmed its uniform distribution. The optical bandgap of CZTS TU-10 was found to be 1.52 eV. XPS results revealed Cu2+, Zn2+, Sn4+, and S2- oxidation states for CZTS TU-10. Cyclic voltammetry of CZTS TU-10 showed the pseudocapacitive nature and the specific capacitance of 389 Fg-1 at 10 mV/s. Furthermore, the photocatalytic activity of the surfactant-free CZTS TU-10 nanostructures was tested using methylene blue (MB) and crystal violet (CV) degradation under visible light irradiation, and the maximum photodegradation efficiencies achieved were at 89% and 93%, respectively, at 70 min. Furthermore, antibacterial studies confirmed that CZTS TU-10 nanostructures produced a high zone of inhibition against Vibrio parahaemolyticus. The results implied that the CZTS nanostructures could be considered efficient for energy storage and photocatalytic application.
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References
Jabeen, U., Shah, S.M., Aamir, M. and Ahmad, I., 2021. Grafting and co-grafting of dyes on Cd-doped ZnS nanocrystals and their application on dye-sensitized solar cells. Bulletin of Materials Science, 44, https://doi.org/10.1007/s12034-021-02575-3.
Zainol, N., Aziz, N.H., Jazlan, C.A.I.C. and Razahazizi, N.A., 2023. The application of design of experiments in the hatchery wastewater treatment through biological method. Current Applied Science and Technology, 23(2), https://doi.org/10.55003/cast.2022.02.23.003.
Bhat, K.S. and Nagaraja, H.S., 2019. Morphology-dependent electrochemical performances of nickel hydroxide nanostructures. Bulletin of Materials Science, 42(6), https://doi.org/10.1007/s12034-019-1951-9.
Reddy, B.J., Vickraman, P. and Justin, A.S., 2019. A facile synthesis of novel α-ZnMoO4 microspheres as electrode material for supercapacitor applications. Bulletin of Materials Science, 42(2), https://doi.org/10.1007/s12034-019-1749-9.
Samiei, E., Mohammadi, S., Torkzadeh-Mahani, M. and Askari, M.B., 2021. Preparation and characterization of ZnCo2O4 as a binary transitional metal oxide towards pseudocapacitor electrode materials. Brazilian Journal of Physics, 51, 420-428.
Devaraj, S. and Munichandraiah, N., 2008. Effect of crystallographic structure of MnO2 on its electrochemical capacitance properties. The Journal of Physical Chemistry C, 112(11), 4406-4417.
Zhang, L.L. and Zhao, X.S., 2009. Carbon-based materials as supercapacitor electrodes. Chemical Society Reviews, 38(9), 2520-2531.
Iqbal, M.W., Faisal, M.M., Hassan, H., Afzal, A.M., Aftab, S., Zahid, T. and Rehman, A., 2022. Facile hydrothermal synthesis of high-performance binary silver-cobalt-sulfide for supercapattery devices. Journal of Energy Storage, 52, https://doi.org/10.1016/j.est.2022.104847.
Tarish, S., Xu, Y., Wang, Z., Mate, F., Al-Haddad, A., Wang, W. and Lei, Y., 2017. Highly efficient biosensors by using well-ordered ZnO/ZnS core/shell nanotube arrays. Nanotechnology, 28(40), https://doi/org/10.1088/1361-6528/aa82b0.
Li, B., Zheng, M., Xue, H. and Pang, H., 2016. High performance electrochemical capacitor materials focusing on nickel based materials. Inorganic Chemistry Frontiers, 3(2), 175-202.
Sarkar, S., Das, B., Midya, P.R., Das, G.C. and Chattopadhyay, K.K., 2015. Optical and thermoelectric properties of chalcogenide based Cu2NiSnS4 nanoparticles synthesized by a novel hydrothermal route. Materials Letters, 152, 155-158.
Gurav, K.V., Pawar, S.M., Shin, S.W., Surayawanshi, M.P., Agawane, G.L., Patil, P.S., Moon, J.H., Yun, J.H. and Kim, J.H., 2013.
Electrosynthesis of CZTS films by sulfurization of CZT precursor: Effect of soft annealing treatment. Applied Surface Science, 283, 74-80.
Norris, D.J., Yao, N., Charnock, F.T. and Kennedy, T.A., 2001. High-quality manganese-doped ZnSe nanocrystals. Nano Letters, 1(1), 3-7.
Phaltane, S.A., Vanalakar, S.A., Bhat, T.S., Patil, P.S., Sartale, S.D. and Kadam, L.D., 2017. Photocatalytic degradation of methylene blue by hydrothermally synthesized CZTS nanoparticles. Journal of Materials Science: Materials in Electronics, 28, 8186-8191.
Gurav, K.V., Yun, J.H., Pawar, S.M., Shin, S.W., Suryawanshi, M.P., Kim, Y.K., Agawane, G.L., Patil, P.S. and Kim, J.H., 2013. Pulsed electrodeposited CZTS thin films: Effect of duty cycle. Materials Letters, 108, 316-319.
Zaberca, O., Oftinger, F., Chane-Ching, J.Y., Datas, L., Lafond, A., Puech, P., Balocchi, A., Lagarde, D. and Marie, X., 2012. Surfactant-free CZTS nanoparticles as building blocks for low-cost solar cell absorbers. Nanotechnology, 23(18), https://doi.org/10.1088/0957-4484/23/18/185402.
Patil, U., Dhanasekar, M., Kadrekar, R., Arya, A., Bhat, S.V. and Late, D.J., 2022. Efficient humidity sensor based on surfactant free Cu2ZnSnS4 nanoparticles. Ceramics International, 48(19), 28898- 28905.
Yu, X., Shavel, A., An, X., Luo, Z., Ibáñez, M. and Cabot, A., 2014. Cu2ZnSnS4-Pt and Cu2ZnSnS4-Au heterostructured nanoparticles for photocatalytic water splitting and pollutant degradation. Journal of the American Chemical Society, 136(26), 9236-9239, https://doi.org/10.1021/ja502076b.
Quinson, J., 2021. Surfactant-free precious metal colloidal nanoparticles for catalysis. Frontiers in Nanotechnology, 3, https://doi.org/10.3389/fnano.2021.770281.
Choudhary, S., Sahu, K., Bisht, A., Singhal, R. and Mohapatra, S., 2020. Template-free and surfactant-free synthesis of CeO2 nanodiscs with enhanced photocatalytic activity. Applied Surface Science, 503, https://doi.org/10.1016/j.apsusc.2019.144102.
Harinipriya, S., Cassian, H. and Sudha, V., 2021. Colloidal CCTS nanoparticle synthesis by solution method for solar photovoltaic applications. Journal of Materials Research and Technology, 15, 3558- 3569.
Zaman, M.B., Mir, R.A. and Poolla, R., 2019. Growth and properties of solvothermally derived highly crystalline Cu2ZnSnS4 nanoparticles for photocatalytic and electrocatalytic applications. International Journal of Hydrogen Energy, 44(41), 23023-23033.
Chaudhari, V.P., Roy, S.M., Chaudhuri, T.K. and Roy, D.R., 2022. Synthesis, characterization and significant antimicrobial properties of CZTS nanoparticles against pathogenic strains. Journal of the Indian Chemical Society, 99(3), https://doi.org/10.1016/j.jics.2022.100351.
Robati, S.M., Imani, M. and Tadjarodi, A., 2018. Ultrafast synthesis of crystalline Cu2ZnSnS4 nanoparticles by solid state microwave heating technique and study of their electrochemical behavior. Materials Letters, 225, 9-12.
Paraye, A., Ramachandran, M. and Selvam, N.V., 2021. Facile ultrasound-assisted synthesis of copper zinc tin sulfide chalcogenide nanoparticles for thin film solar cell applications. Periodica Polytechnica Chemical Engineering, 65(1), 42-49.
Shi, B., Liu, W., Zhu, K. and Xie, J., 2017. Synthesis of flower-like copper sulfides microspheres as electrode materials for sodium secondary batteries. Chemical Physics Letters, 677, 70-74.
Rawat, K. and Shishodia, P.K., 2017. Structural and optical properties of sol-gel derived Cu2ZnSnS4 nanoparticles, Advanced Powder Technology 28(2), 611-617.
Long, B., Cheng, S., Ye, D., Yue, C. and Liao, J., 2019. Mechanistic aspects of preheating effects of precursors on characteristics of Cu2ZnSnS4 (CZTS) thin films and solar cells. Materials Research Bulletin, 115, 182-190.
Liqiang, J., Yichun, Q., Baiqi, W., Shudan, L., Baojiang, J., Libin, Y., Wei, F., Honggang, F. and Jiazhong, S., 2006, Review of photoluminescence performance of nano-sized semiconductor materials and its relationships with photocatalytic activity. Solar Energy Materials and Solar Cells, 90(12), 773-787.
Yang, Y., Ding, Y., Zhang, J., Liang, N., Long, L. and Liu, J., 2022. Insight into the growth mechanism of mixed phase CZTS and the photocatalytic Performance. Nanomaterials, 12(9), https://doi.org/10.3390/nano12091439.
Waluś, E., Manecki, M., Cios, G. and Tokarski, T., 2021. Effect of a sulfur precursor on the hydrothermal synthesis of Cu2MnSnS4. Materials, 14(13), https://doi.org/10.3390/ma14133457.
Rovelli, L., Tilley, S.D. and Sivula, K., 2013. Optimization and stabilization of electrodeposited Cu2ZnSnS4 photocathodes for solar water reduction. ACS Applied Materials and Interfaces, 5(16), 8018-8024.
Verma, S.K., Agrawal, V., Jain, K., Pasricha, R. and Chand, S., 2013, Green synthesis of nanocrystalline Cu2ZnSnS4 powder using the hydrothermal route. Journal of Nanoparticles, 2013, https://doi.org/10.1155/2013/685836.
Bahramzadeh, S., Abdizadeh, H. and Golobostanfard, M.R., 2015. Controlling the morphology and properties of solvothermal synthesized Cu2ZnSnS4 nanoparticles by solvent type. Journal of Alloys and Compounds, 642, 124-130.
Winkler, M.T., Wang, W., Gunawan, O., Hovel, H.J., Todorov, T.K. and Mitzi, D.B., 2014. Optical designs that improve the efficiency of Cu2ZnSn(S,Se)4 solar cells. Energy and Environmental Science, 7(3), 1029-1036.
Shafi, M.A., Khan, L., Ullah, S., Bouich, A., Ullah, H. and Mari, B., 2022. Synthesis of CZTS kesterite by pH adjustment in order to improve the performance of CZTS thin film for photovoltaic applications. Micro and Nanostructures, 164, https://doi.org/10.1016/j.spmi.2022.107185.
Shalabayev, Z., Baláz, M., Daneu, N., Dutková, E., Bujňáková, Z., Kaňuchová, M., Danková, Z., Balážová, L., Urakaev, F., Tkáčiková, L. and Burkitbayev, M., 2019. Sulfur-mediated mechanochemical synthesis of spherical and needle-like copper sulfide nanocrystals with antibacterial activity. ACS Sustainable Chemistry and Engineering, 7(15), 12897-12909.
Guo, Y., Wei, J., Yang, T., Lv, Z. and Xu, Z., 2019. Manipulation of surface plasmon resonance for high photocatalytic activity of Ag-Bi2WO6 hetero-architecture. Optik, 180, 285-294.
Lixiong, Y., Dan, W., Jianfeng, H., Liyun, C., Haibo, O., Jianpeng, W. and Xiang, Y., 2015. Microwave hydrothermal synthesis and photocatalytic activities of morphology-controlled ZnS crystallites. Ceramics International, 41(2), 3288-3292.
Singh, O.P., Parmar, R., Gour, K.S., Dalai, M.K., Tawale, J., Singh, S.P. and Singh, V.N., 2015. Synthesis and characterization of petal type CZTS by stacked layer reactive sputtering. Superlattices and Microstructures, 88, 281-286.
Ghosh, A., Biswas, A., Thangavel, R. and Udayabhanu, G., 2016. Photo-electrochemical properties and electronic band structure of kesterite copper chalcogenide Cu 2–II–Sn–S 4 (II= Fe, Co, Ni) thin films. RSC Advances, 6(98), 96025-96034.
Keller, A.A., Vosti, W., Wang, H. and Lazareva, A., 2014. Release of engineered nanomaterials from personal care products throughout their life cycle. Journal of Nanoparticle Research, 16, 1-10.
Henríquez, R., Nogales, P.S., Moreno, P.G., Cartagena, E.M., Bongiorno, P.L., Navarrete-Astorga, E. and Dalchiele, E.A., 2023. One-step hydrothermal synthesis of Cu2ZnSnS4 nanoparticles as an efficient visible light photocatalyst for the degradation of congo red azo dye. Nanomaterials, 13(11), https://doi.org/10.3390/nano13111731.
Patil, S.S., Mane, R.M., Mali, S.S., Hong, C.K. and Bhosale, P.N., 2020. Facile designing and assessment of photovoltaic performance of hydrothermally grown kesterite Cu2ZnSnS4 thin films: influence of deposition time. Solar Energy, 201, 102-115.
Zaman, M.B., Mir, R.A. and Poolla, R., 2019. Growth and properties of solvothermally derived highly crystalline Cu2ZnSnS4 nanoparticles for photocatalytic and electrocatalytic applications. International Journal of Hydrogen Energy, 44(41), 23023-23033.
Mkawi, E.M., Al-Hadeethi, Y., Al-Hartomy, O. and Bekyarova, E., 2020. Size-controlling of Cu2ZnSnS4 nanoparticles: Effects of stabilizing/reducing agents on material properties. Results in Physics, 19, https://doi.org/10.1016/j.rinp.2020.103407.
Mirbagheri, N., Engberg, S., Crovetto, A., Simonsen, S.B., Hansen, O., Lam, Y.M. and Schou, J., 2016. Synthesis of ligand-free CZTS nanoparticles via a facile hot injection route. Nanotechnology, 27(18), https://doi.org/10.1088/0957-4484/27/18/185603.
Khammar, M., Ynineb, F., Guitouni, S., Bouznit, Y. and Attaf, N., 2020. Crystallite size and intrinsic strain contribution in band gap energy redshift of ultrasonic-sprayed kesterite CZTS nanostructured thin films. Applied Physics A, 126(6), https://doi.org/10.1007/s00339-020-03591-6.
Rajesh, G., Muthukumarasamy, N., Subramanian, E.P., Venkatraman, M.R., Agilan, S., Ragavendran, V., Thambidurai, M., Velumani, S., Yi, J. and Velauthapillai, D., 2015. Solution-based synthesis of high yield CZTS (Cu2ZnSnS4) spherical quantum dots. Superlattices and Microstructures, 77, 305-312.
Zhao, Y., Yan, J., Huang, Y., Lian, J., Qiu, J., Bao, J., Cheng, M., Xu, H., Li, H. and Chen, K., 2018. Interfacial self-assembly of monolayer Mg-doped NiO honeycomb structured thin film with enhanced performance for gas sensing. Journal of Materials Science: Materials in Electronics, 29, 11498-11508.
Premkumar, V.K., Sivakumar, G., Dinesh, S. and Barathan, S., 2017. Facile hydrothermal synthesis of cobalt stannate (Co2SnO4) nano particles for electrochemical properties. Journal of Materials Science: Materials in Electronics, 28, 4780-4787.
Farzi, M., Moradi, M., Hajati, S., Toth, J. and Kazemzadeh, A., 2021. Synthesis of rod-like ternary Cu (Cd)-In-S and quaternary Cu-Cd-In-S by controlled ion exchange of MIL-68 (In) derived indium sulfide for high energy-storage capacitor. Synthetic Metals, 278, https://doi.org/10.1016/j.synthmet.2021.116815.
Sarkar, S., Howli, P., Das, B., Das, N.S., Samanta, M., Das, G.C. and Chattopadhyay, K.K., 2017. Novel quaternary chalcogenide/reduced graphene oxide-based asymmetric supercapacitor with high energy density. ACS Applied Materials and Interfaces, 9(27), 22652-22664.
Fan, J., Li, T. and Heng, H., 2016. Hydrothermal growth of ZnO nanoflowers and their photocatalyst application. Bulletin of Materials Science, 39, 19-26.
Zhou, Z., Zhang, P., Lin, Y., Ashalley, E., Ji, H., Wu, J., Li, H. and Wang, Z., 2014. Microwave fabrication of Cu2ZnSnS4 nanoparticle and its visible light photocatalytic properties. Nanoscale Research Letters, 9, https://doi.org/10.1186/1556-276X-9-477.
Manjula, S., Sarathkumar, A. and Sivakumar, G., 2023. Hydrothermally synthesized Cu2ZnSnS4 nanoparticles for photocatalytic degradation of Rhodamine B dye. Journal of Nano Research, 79, 25-36.
Sawant, J.P., Rajput, R., Patil, S., Ryu, J., Patil, D.R. and Kale, R.B., 2021. Photocatalytic activities of hydrothermal synthesized copper zinc tin sulfide nanostructures. Journal of Materials Science: Materials in Electronics, 32, 22803-22812.
Sheebha, I., Venugopal, V., James, J., Maheskumar, V., Sakunthala, A. and Vidhya, B., 2020. Comparative studies on hierarchical flower like Cu2XSnS4 [X= Zn, Ni, Mn & Co] quaternary semiconductor for electrocatalytic and photocatalytic applications. International Journal of Hydrogen Energy, 45(15), 8139-8150.
Semalti, P., Sharma, V. and Sharma, S.N., 2021. A novel method of water remediation of organic pollutants and industrial wastes by solution-route processed CZTS nanocrystals. Journal of Materiomics, 7(5), 904-919.
Hou, X., Li, Y., Yan, J.J. and Wang, C.W., 2014. Highly efficient photocatalysis of p-type Cu2ZnSnS4 under visible-light illumination. Materials Research Bulletin, 60, 628-633.
Kumar, R.S., Maddirevula, S., Easwaran, M., Dananjaya, S.H.S. and Kim, M.D., 2015. Antibacterial activity of novel Cu2ZnSnS4 nanoparticles against pathogenic strains. RSC Advances, 5(129), 106400-106405.
Khashan, K.S., Sulaiman, G.M., Ameer, F.A.K.A. and Napolitano, G., 2016. Synthesis, characterization and antibacterial activity of colloidal NiO nanoparticles. Pakistan Journal of Pharmaceutical Sciences, 29(2), 541-546.
Chaudhari, V.P., Roy, S.M., Chaudhuri, T.K. and Roy, D.R., 2022. Synthesis, characterization and significant antimicrobial properties of CZTS nanoparticles against pathogenic strains. Journal of the Indian Chemical Society, 99(3), https://doi.org/10.1016/j.jics.2022.100351.
Chaudhari, V.P., Rajput, K., Roy, S.M., Chaudhuri, T.K. and Roy, D.R., 2022. Experimental and first- principles investigation on the structural, electronic and antimicrobial properties of nickel hydroxide nanoparticles. Journal of Physics and Chemistry of Solids, 160, https://doi.org/10.1016/j.jpcs.2021.110367.
Verma, A., Uzun, O., Hu, Y., Hu, Y., Han, H.S., Watson, N., Chen, S., Irvine, D.J. and Stellacci, F., 2008. Surface-structure-regulated cell-membrane penetration by monolayer-protected nanoparticles. Nature Materials, 7(7), 588-595.
Nel, A.E., Mädler, L., Velegol, D., Xia, T., Hoek, E.M., Somasundaran, P., Klaessig, F., Castranova, V. and Thompson, M., 2009. Understanding bio physico chemical interactions at the nano-bio interface. Nature Materials, 8(7), 543-557.
Yılmaz, G.E, Göktürk, I., Ovezova, M., Yılmaz, F., Kılıç, S. and Denizli, A., 2023. Antimicrobial nanomaterials: a review. Hygiene, 3(3), 269-290.
Franco, D., Calabrese G., Guglielmino, S.P.P. and Conoci, S., 2022. Metal-based nanoparticles: Antibacterial mechanisms and biomedical application. Microorganisms,10(9), https://doi.org/10.3390/microorganisms10091778.