Study of Optimal Biodiesel Production from Waste Frying Oils for Community, and Prototype of Biodiesel Reactor Using Biomass Energy

Authors

  • Arrisa Sopajarn Agricultural Machinery Engineering, Department of Industrial, Rattaphum College, Rajamangala University of Technology Srivijaya, Tachamuang, Rattaphum, Songkhla 90180, Thailand.
  • Jakkrapong Jitjamnong Petroleum Technology, Faculty of Industrial Education and Technology, Rajamangala University of Technology Srivijaya, Boyang, Muang, Songkhla 90000, Thailand.
  • Naparat Kasetsomboon Petroleum Technology, Faculty of Industrial Education and Technology, Rajamangala University of Technology Srivijaya, Boyang, Muang, Songkhla 90000, Thailand.
  • Suhdee Niseng Agricultural Machinery Engineering, Department of Industrial, Rattaphum College, Rajamangala University of Technology Srivijaya, Tachamuang, Rattaphum, Songkhla 90180, Thailand.

Keywords:

waste cooking oil, ester, transesterification, response surface methodology

Abstract

This research aimed to examine biodiesel synthesis from waste of Khaoroopchang Municipality, Songkhla Province. Waste cooking oil with acid value less than 2 mgKOH/g collected from markets was used. The four parameters: molar ratio of alcohol to oils (3:1-15:1), amount of catalyzed (1-5 %wt.), reaction time (min), reaction temperature (50-70 °C), and impeller speed (300 rpm) were investigated. The response surface methodology with central composite design (CCD) was adopted to optimize the condition of base-catalyzed transesterification in lap-scale. The result indicated that under condition of 7.73:1 of molar ratio of alcohol to oils, 3.97 %wt. of KOH, 60.54 min of reaction time, and 55 °C of reaction time, biodiesel purity was obtained comparably for commercial biodiesel standard. Then the data in lap-scale were used for studying biodiesel production system for community from waste frying oils by using biomass energy for heating the reaction. After testing the system with the same optimized condition in lab-scale, methyl ester purity was achieved 96.83 wt.%. This biodiesel was suitable for using in agricultural engine and diesel engine for long-tailed fishing boat.

References

Falowo, O.A., Apanisile, O.E., Aladelusi, A.O., Adeleke, A.E., Oke, M.A., Enamhanya, A., Latinwo, L.M. and Betiku, E. 2021. Influence of nature of catalyst on biodiesel synthesis via irradiation-aided transesterification of waste cooking oil-honne seed oil blend: Modeling and optimization by Taguchi design method. Energy Conversion and Management: X 12: 100119.

Inthachai, S. and Roschat, W. 2019. The Performance Testing of Biodiesel Oil Produced from Waste Cooking Oil by Using a prototype Solar Reactor for Agricultural Diesel Engines. Journal of Materials Science and Applied Energy 8(2): 398-407.

Jairuan, W., Pairintra, R. and Sudapraset, K. 2017. Biodiesel production by transesterification from chicken fat. RMUTSB Academic Journal 5(1): 41-49. (in Thai)

Kattiyawan, T. 2016. Comparison and Improvement of Biodiesel Production Process from Used Vegetable Oil (A Case Study of Bangnak Community). Princess of Naradhiwas University Journal 8(1): 70-78. (in Thai)

Lestari, S., Maki-Arvela, P., Beltramini, J., Max Lu, G.Q. and Murzin, D.Y. 2009. Transforming Triglycerides and Fatty Acids into Biofuels. ChemSusChem 2(12): 1109-1119.

Linganiso, E.C., Tlhaola, B., Magagula, L.P., Dziike, S., Linganiso, L.Z., Motaung, T.E., Motolo, N. and Tetana, Z.N. 2022. Biodiesel Production from Waste Oils: A south African Outlook. Sustainability 14: 1-21.

Ma, F. and Hanna, M.A. 1999. Biodiesel production: a review. Bioresource Technology 70: 1-15.

Mangwandi, C., Adams, M.J., Hounslow, M.J. and Salman, A.D. 2010. Effect of impeller speed on mechanical and dissolution properties of high-shear granular. Chemical Engineering Journal 164: 305-315.

Mueanmas, C., Nikhom, R., Sopajarn, J. and Petchkaew, A. 2018. A Study of Influence Factors Affecting to Esterification Reaction of Waste Coffee Grounds Oil using Response Surface Methodology. Thaksin University Journal 21(3) (Special issue): 140-148. (in Thai)

Niseng, S. 2013. Two-stage biodiesel production system from high free fatty acid crude palm oil using circulation through static mixer. Master Thesis of Engineering (Mechanical Engineering), Prince of Songkla University. (in Thai)

Niseng, S. 2018. Development of biodiesel production reactor from used vegetable oil using 45° two-blade paddle coupled with 6-blade disc turbine. Kasetsart Engineering Journal 31(105): 29-38. (in Thai)

Phoosakul, P. 2011. Study of Using CaO as Catalyst for Biodiesel Production with Refluxing Alcohol. Master Thesis of Engineering (Chemical Engineering), Prince of Songkla University. (in Thai)

Quah, R.V., Tan, Y.H., Mubarak, N.M., Kansedo, J., Khalid, M., Abdullah, E.A. and Abdullah, M.O. 2020. Magnetic biochar derived from waste palm kernel shell for biodiesel production via sulfonation. Waste Management 118: 626-636.

Rahadianti, E.S., Yerizam, Y. and Martha, M. 2018. Biodiesel Production from Waste Cooking Oil. Indonesian Journal of Fundamental and Applied Chemistry 3(3): 70-82.

Roschat, W., Butthichack, P., Daengdet, N., Phewphong, S., Kaewpuang, T., Moonsin, P., Yoosuk, B. and Promarak, V. 2020. Kinetic study of biodiesel production at room temperature based on eggshell-derived CaO as basic heterogeneous catalyst. Engineering and Applied Science Research 47(4): 361-373.

Santadkha, T. and Santikunaporn, M. 2018. Biodiesel Production from Waste Cooking Oil Using KOH with Microwave Heating. Science and Technology Journal 26(6): 1041-1048. (in Thai)

Singhasiri, T. 2014. Optimization of biodiesel production from chicken fat using response surface methodology. Journal of Energy Research 11(2): 54-65. (in Thai)

Somnuk, K., Niseng, S. and Prateepchaikul, G. 2014. Optimization of high free fatty acid reduction in mixed crude palm oils using circulation process through static mixer reactor and pilot-scale of two-step process. Energy Conversion and Management 80: 374-381.

Somnuk, K., Smithmaitre, P. and Prateepchaikul, G. 2013. Optimization of continuous acid-catalyzed esterification for free fatty acids reduction in mixed crude palm oil using static mixer coupled with high-intensity ultrasonic irradiation. Energy Conversion and Management 68: 193-199.

Suppalakpanya, K., Rattanawilai, S.B. and Thongurai, C. 2010. Production of ethyl ester from crude palm oil by two-step reaction with a microwave system. Fuel 89: 2140-2144.

Suzihaque, M.U.H., Syazwina, N., Alwi, H., Ibrahim, U.K., Abdullah, S. and Haron, N. 2022. A sustainability study of the processing of kitchen waste as a potential source of biofuel: Biodiesel production from waste cooking oil (WCO). Materials Today: Proceedings 63(Supplement 1): 484-489.

The Department of Energy Business. 2006. Biodiesel Characteristics and Quality for Agricultural Engines (Community Biodiesel) B.E. 2549. Available source: http://elaw.doeb.go. th/document_ doeb/TH/77_0001.pdf, November 12, 2022. (in Thai)

Thunyaratchatanon, C., Luengnaruemitcha, A., Jitjamnong, J., Chollacoop, N., Chen, S.Y. and Yoshimura, Y. 2018. Influence of Alkaline and Alkaline Earth Metal Promoters on the Catalytic Performance of Pd-M/SiO2 (M = Na, Ca, or Ba) Catalysts in the Partial Hydrogenation of Soybean Oil-Derived Biodiesel for Oxidative Stability Improvement. Energy & Fuels 32(9): 9744-9755.

Yaqoob, H., Teoh, Y.H., Sher, F., Farooq, M.U., Jamil, M.A., Kausar, Z., Sabah, N.U., Shah, M.F., Rehman, H.Z.U. and Rehman, A.U. 2021. Potential of Waste Cooking Oil Biodiesel as Renewable Fuel in Combustion Engines: A Review. Energies 14(9): 1-20.

Published

2023-12-26

How to Cite

Sopajarn, A., Jitjamnong, J., Kasetsomboon, N., & Niseng, S. (2023). Study of Optimal Biodiesel Production from Waste Frying Oils for Community, and Prototype of Biodiesel Reactor Using Biomass Energy. Recent Science and Technology, 15(3), 761–777. Retrieved from https://li01.tci-thaijo.org/index.php/rmutsvrj/article/view/249449