The Effect of Vulcanization Temperature on the Properties of Natural Rubber Latex to Prepare the Suturing Training Pad

Authors

  • Korn Taksapattanakul Faculty of Science and Technology, Princess of Naradhiwas University, Muang Narathiwat, Narathiwat 96000, Thailand.
  • Suchada Saengwiman Faculty of Science and Technology, Princess of Naradhiwas University, Muang Narathiwat, Narathiwat 96000, Thailand.
  • Arom Puteh Faculty of Science and Technology, Princess of Naradhiwas University, Muang Narathiwat, Narathiwat 96000, Thailand.
  • Niasmihan Niseng PNU Wittayanusorn School, Faculty of Science and Technology, Princess of Naradhiwas University, Muang Narathiwat, Narathiwat 96000, Thailand.
  • Suchada Srichai PNU Wittayanusorn School, Faculty of Science and Technology, Princess of Naradhiwas University, Muang Narathiwat, Narathiwat 96000, Thailand.

Keywords:

suturing material, medical training lab, natural rubber, skin simulation, suture

Abstract

This study focuses on the controlled curing method for preparing natural rubber latex as a suturing training pad. Local natural rubber latex was transformed into pre-vulcanized rubber latex using a chemical. The natural rubber sheets were cured at temperatures of 30 ± 2 °C, 40 ± 2 °C, and 50 ± 2 °C for 7 days under controlled conditions. Various properties, including stress-strain curves, hardness, crosslink density, swelling, and crosslinking behavior, analyzed using FT-IR spectra, were examined. The FT-IR spectra indicated a decrease in the signal of the C=C bond and an increase in the C-S bond, demonstrating the crosslinking behavior. As the curing temperature increased, crosslinking also increased, resulting in enhanced stress-strain properties at break, higher Young's modulus, greater strain hardening, and increased hardness. Additionally, crosslink density increased while swelling decreased. A curing temperature of 30 ± 2 °C was selected for preparing the natural rubber sheet for use as a suturing training pad. The performance of this rubber sheet was tested and compared with a commercial silicone skin suture practice sheet. The results showed that no cracking occurred around the pinholes, and the rubber surface could be sutured without tearing. A nylon suture placed on the rubber surface demonstrated a tight closure, similar to that of the silicone skin suture practice sheet.

References

Boyajian, M.K., Lubner, R.J., Roussel, L.O., Crozier, J.W., Ryder, B.A. and Woo, A.S. 2019. A novel suture training device to innovate the surgical curriculum in medical school. Plastic and Reconstructive Surgery 7(8): 121-122.

Bornstein, D. and Pazur, R.J. 2020. The sulfur reversion process in natural rubber in terms of crosslink density and crosslink density distribution. Polymer Testing 88: 106524.

Coran, A.Y. 1965. Vulcanization. part VII. kinetics of sulfur vulcanization of natural rubber in presence of delayed-action accelerators. Rubber Chemistry and Technology 38(1): 1-14.

Cheung, C.L., Looi, T., Lendvay, T.S., Drake, J.M. and Farhat, W.A. 2014. Use of 3-dimensional printing technology and silicone modeling in surgical simulation: development and face validation in pediatric laparoscopic pyeloplasty. Journal of Surgical Education 71(5): 762-767.

Roylance, D. 2001. Stress-strain curves. Massachusetts Institute of Technology study, Cambridge.

Gallagher, P.O., Bishop, N. and Dubrowski, A. 2020. Investigating the perceived efficacy of a silicone suturing task trainer using input from novice medical trainees. Cureus 12(1): e6612.

Gonzalez-Navarro, A.R., Quiroga-Garza, A., Acosta-Luna, A.S., Salinas-Alvarez, Y., Martinez-Garza, J.H., Garza-Castro, O. de la., Gutierrez-de la O, J., Fuente-Villarreal, D. de la., Elizondo-Omaña, R.E. and Guzman-Lopez, S. 2021. Comparison of suturing models: the effect on perception of basic surgical skills. BMC Medical Education 21: 250.

Ige, O.O., Umoru, L.E. and Aribo, S. 2012. Natural Products: A Minefield of Biomaterials. International Scholarly Research Notices 983062: 20.

John, P.L., Peter, S.T., Satyen, G., Mark, W., Vincent, B.H. and Peter, L. 2018. Using 3D printing (additive manufacturing) to produce low-cost simulation models for medical training. Military Medicine 183(1): 73-77.

Khantasa-Ard, P. 2024. Polyurethane leather as a suture training model. Cureus 16(10): 1-9.

Kishore, K. and Pandey, H.K. 1986. Spectral studies on plant rubbers. Progress in Polymer Science 12(1-2): 155-178.

Kumnuantip, C. and Sombatsompop, N. 2003. Dynamic mechanical properties and swelling behaviour of NR/reclaimed rubber blends. Materials Letters 57(21): 3167-3174.

Kruželák, J., Sýkora, R. and Hudec, I. 2016. Sulphur and peroxide vulcanisation of rubber compounds -overview. Chemical Papers 70(12): 1533-1555.

La, T.M. and Caruso, C. 2013. The animal model in advanced laparoscopy resident training. Surgical Laparoscopy Endoscopy & Percutaneous Techniques 23(3): 271-275.

Lu, F.J. and Hsu, S.L. 1987. A vibrational spectroscopic analysis of the structure of natural rubber. Rubber Chemistry and Technology 60: 647-658.

Milani, G., Leroy, E., Milani, F. and Deterre, R. 2013. Mechanistic modeling of reversion phenomenon in sulphur cured natural rubber vulcanization kinetics. Polymer Testing 32(6): 1052-1063.

Panmanee, P., Okhawilai, M., Mora, P., Jubsilp, C., Karagiannidis, P. and Rimdusit, S. 2023. Development of a new birthing model material based on silicone rubber/natural rubber blend. Polymer Testing 117: 107849.

Paul, J.F. and John, R. 1943. Statistical mechanics of cross-linked polymer networks II. swelling. The Journal of Chemical Physics 11(11): 521-526.

Posadas, P., Fernández, T.A., Valentín, J.L., Rodríguez, A. and González, L. 2010. Effect of the temperature on the kinetic of natural rubber vulcanization with the sulfur donor agent dipentamethylene thiuram tetrasulphide. Journal of Applied Polymer Science 115: 692-701.

Rai, A.K., Singh, R., Singh, K.N. and Singh, V.B. 2006. FTIR, Raman spectra and ab initio calculations of 2-mercaptobenzothiazole. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy 63(2): 483-490.

Sébastien, R., Siriluck, L., Laurent, V., Sainte, B.J. and Frédéric, B. 2015. Investigating natural rubber composition with fourier transform infrared (FT-IR) spectroscopy: a rapid and non-destructive method to determine both protein and lipid contents simultaneously. Polymer Testing 43: 83-93.

Serdinšek, T., Andrić, B.Ž. and But, I. 2019. A new affordable and easy-to-make pelvic model for training in complex urogynecological laparoscopic procedures. International Urogynecology Journal 30: 1497-1501.

Smitthipong, W., Tantatherdtam, R., Rungsanthien, K., Suwanruji, P., Klanarong, S., Radabutra, S., Thanawan, S., Vallat, M.F., Nardin, M., Mougin, K., Chollakup, R. 2013. Effect of non-rubber components on properties of sulphur crosslinked natural rubbers. Advanced Materials Research 844: 345-348.

Suntako, R. 2014. Cure characteristics and mechanical properties of ZnO nanoparticles as activator in unfilled natural rubber. Advanced Materials Research 1044-1045: 23-26.

Wei, F.C., Anas, E., Takumi, Y., Jerrod, K., Grace, L.N. and Lawrence, W.T. 2014. A novel super microsurgery training model: the chicken thigh. Journal of Plastic and Reconstructive Surgery 67(7): 973-978.

Wietor, J.L. and Sijbesma, R. 2008. A self-healing elastomer. Angewandte Chemie International Edition 47(43): 8161-8163.

Xu, C., Cao, L., Lin, B., Liang, X. and Chen, Y. 2016. Design of self-healing supramolecular rubbers by introducing ionic cross-links into natural rubber via a controlled vulcanization. ACS Applied Materials & Interfaces Journal 8(27): 17728-17737.

Downloads

Published

2024-12-26

How to Cite

Taksapattanakul, K., Saengwiman, S., Puteh, A., Niseng, N., & Srichai, S. (2024). The Effect of Vulcanization Temperature on the Properties of Natural Rubber Latex to Prepare the Suturing Training Pad. Recent Science and Technology, 17(1), 264500. retrieved from https://li01.tci-thaijo.org/index.php/rmutsvrj/article/view/264500

Issue

Section

Research Article