The Effect of Vulcanization Temperature on the Properties of Natural Rubber Latex to Prepare the Suturing Training Pad
Keywords:
suturing material, medical training lab, natural rubber, skin simulation, sutureAbstract
This study focuses on the controlled curing method for preparing natural rubber latex as a suturing training pad. Local natural rubber latex was transformed into pre-vulcanized rubber latex using a chemical. The natural rubber sheets were cured at temperatures of 30 ± 2 °C, 40 ± 2 °C, and 50 ± 2 °C for 7 days under controlled conditions. Various properties, including stress-strain curves, hardness, crosslink density, swelling, and crosslinking behavior, analyzed using FT-IR spectra, were examined. The FT-IR spectra indicated a decrease in the signal of the C=C bond and an increase in the C-S bond, demonstrating the crosslinking behavior. As the curing temperature increased, crosslinking also increased, resulting in enhanced stress-strain properties at break, higher Young's modulus, greater strain hardening, and increased hardness. Additionally, crosslink density increased while swelling decreased. A curing temperature of 30 ± 2 °C was selected for preparing the natural rubber sheet for use as a suturing training pad. The performance of this rubber sheet was tested and compared with a commercial silicone skin suture practice sheet. The results showed that no cracking occurred around the pinholes, and the rubber surface could be sutured without tearing. A nylon suture placed on the rubber surface demonstrated a tight closure, similar to that of the silicone skin suture practice sheet.
References
Boyajian, M.K., Lubner, R.J., Roussel, L.O., Crozier, J.W., Ryder, B.A. and Woo, A.S. 2019. A novel suture training device to innovate the surgical curriculum in medical school. Plastic and Reconstructive Surgery 7(8): 121-122.
Bornstein, D. and Pazur, R.J. 2020. The sulfur reversion process in natural rubber in terms of crosslink density and crosslink density distribution. Polymer Testing 88: 106524.
Coran, A.Y. 1965. Vulcanization. part VII. kinetics of sulfur vulcanization of natural rubber in presence of delayed-action accelerators. Rubber Chemistry and Technology 38(1): 1-14.
Cheung, C.L., Looi, T., Lendvay, T.S., Drake, J.M. and Farhat, W.A. 2014. Use of 3-dimensional printing technology and silicone modeling in surgical simulation: development and face validation in pediatric laparoscopic pyeloplasty. Journal of Surgical Education 71(5): 762-767.
Roylance, D. 2001. Stress-strain curves. Massachusetts Institute of Technology study, Cambridge.
Gallagher, P.O., Bishop, N. and Dubrowski, A. 2020. Investigating the perceived efficacy of a silicone suturing task trainer using input from novice medical trainees. Cureus 12(1): e6612.
Gonzalez-Navarro, A.R., Quiroga-Garza, A., Acosta-Luna, A.S., Salinas-Alvarez, Y., Martinez-Garza, J.H., Garza-Castro, O. de la., Gutierrez-de la O, J., Fuente-Villarreal, D. de la., Elizondo-Omaña, R.E. and Guzman-Lopez, S. 2021. Comparison of suturing models: the effect on perception of basic surgical skills. BMC Medical Education 21: 250.
Ige, O.O., Umoru, L.E. and Aribo, S. 2012. Natural Products: A Minefield of Biomaterials. International Scholarly Research Notices 983062: 20.
John, P.L., Peter, S.T., Satyen, G., Mark, W., Vincent, B.H. and Peter, L. 2018. Using 3D printing (additive manufacturing) to produce low-cost simulation models for medical training. Military Medicine 183(1): 73-77.
Khantasa-Ard, P. 2024. Polyurethane leather as a suture training model. Cureus 16(10): 1-9.
Kishore, K. and Pandey, H.K. 1986. Spectral studies on plant rubbers. Progress in Polymer Science 12(1-2): 155-178.
Kumnuantip, C. and Sombatsompop, N. 2003. Dynamic mechanical properties and swelling behaviour of NR/reclaimed rubber blends. Materials Letters 57(21): 3167-3174.
Kruželák, J., Sýkora, R. and Hudec, I. 2016. Sulphur and peroxide vulcanisation of rubber compounds -overview. Chemical Papers 70(12): 1533-1555.
La, T.M. and Caruso, C. 2013. The animal model in advanced laparoscopy resident training. Surgical Laparoscopy Endoscopy & Percutaneous Techniques 23(3): 271-275.
Lu, F.J. and Hsu, S.L. 1987. A vibrational spectroscopic analysis of the structure of natural rubber. Rubber Chemistry and Technology 60: 647-658.
Milani, G., Leroy, E., Milani, F. and Deterre, R. 2013. Mechanistic modeling of reversion phenomenon in sulphur cured natural rubber vulcanization kinetics. Polymer Testing 32(6): 1052-1063.
Panmanee, P., Okhawilai, M., Mora, P., Jubsilp, C., Karagiannidis, P. and Rimdusit, S. 2023. Development of a new birthing model material based on silicone rubber/natural rubber blend. Polymer Testing 117: 107849.
Paul, J.F. and John, R. 1943. Statistical mechanics of cross-linked polymer networks II. swelling. The Journal of Chemical Physics 11(11): 521-526.
Posadas, P., Fernández, T.A., Valentín, J.L., Rodríguez, A. and González, L. 2010. Effect of the temperature on the kinetic of natural rubber vulcanization with the sulfur donor agent dipentamethylene thiuram tetrasulphide. Journal of Applied Polymer Science 115: 692-701.
Rai, A.K., Singh, R., Singh, K.N. and Singh, V.B. 2006. FTIR, Raman spectra and ab initio calculations of 2-mercaptobenzothiazole. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy 63(2): 483-490.
Sébastien, R., Siriluck, L., Laurent, V., Sainte, B.J. and Frédéric, B. 2015. Investigating natural rubber composition with fourier transform infrared (FT-IR) spectroscopy: a rapid and non-destructive method to determine both protein and lipid contents simultaneously. Polymer Testing 43: 83-93.
Serdinšek, T., Andrić, B.Ž. and But, I. 2019. A new affordable and easy-to-make pelvic model for training in complex urogynecological laparoscopic procedures. International Urogynecology Journal 30: 1497-1501.
Smitthipong, W., Tantatherdtam, R., Rungsanthien, K., Suwanruji, P., Klanarong, S., Radabutra, S., Thanawan, S., Vallat, M.F., Nardin, M., Mougin, K., Chollakup, R. 2013. Effect of non-rubber components on properties of sulphur crosslinked natural rubbers. Advanced Materials Research 844: 345-348.
Suntako, R. 2014. Cure characteristics and mechanical properties of ZnO nanoparticles as activator in unfilled natural rubber. Advanced Materials Research 1044-1045: 23-26.
Wei, F.C., Anas, E., Takumi, Y., Jerrod, K., Grace, L.N. and Lawrence, W.T. 2014. A novel super microsurgery training model: the chicken thigh. Journal of Plastic and Reconstructive Surgery 67(7): 973-978.
Wietor, J.L. and Sijbesma, R. 2008. A self-healing elastomer. Angewandte Chemie International Edition 47(43): 8161-8163.
Xu, C., Cao, L., Lin, B., Liang, X. and Chen, Y. 2016. Design of self-healing supramolecular rubbers by introducing ionic cross-links into natural rubber via a controlled vulcanization. ACS Applied Materials & Interfaces Journal 8(27): 17728-17737.

Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Recent Science and Technology

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
The content and information in the article published in Journal of Rajamangala University of Technology Srivijaya It is the opinion and responsibility of the author of the article. The editorial journals do not need to agree. Or share any responsibility.