Catalytic Study of KMnO4-Zeolite 13X Catalyst for the Synthesis of Glycerol Carbonate from Carbonylation of Glycerol and Urea
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Abstract
This research aims to study KMnO4 loaded on zeolite 13X catalyst synthesized by impregnation for the synthesis of glycerol carbonate from the carbonylation of glycerol and urea by using microwave technique. The catalyst characteristics were determined by FTIR, XRD, and BET. The comparison of the non-catalytic and catalytic using KMnO4-Zeolite 13X as catalysts were studied at concentrations of 10% and 20% by weight per volume in various amounts. The conversion of glycerol, selectivity of glycerol carbonate and yield of glycerol carbonate were determined. The optimum conditions were studied by using a microwave with a power of 130 watts, reaction time of 80 minutes, using 20% w/v of KMnO4-Zeolite 13X catalyst at the amount 2% of glycerol weight. The conversion of glycerol, selectivity and yield of glycerol carbonate were 74.10%, 60.76%, and 45.02%, respectively.
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Man, K.L., Keat, T.L. and Abdul, R.M. 2010. Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances, 28(4), 500-518.
Arbab, M.I., Masjuki, H.H., Varman, M., Kalam, M.A., Imtenan, S. and Sajjad, H. 2013. Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel. Renewable and Sustainable Energy Reviews, 22, 133-147.
Lertlukkanasuk, N., Phiyanalinmat, S., Kiatkittipong, W., Arpornwichanop, A., Aiouache, F. and Assabumrungrat, S.2013. Reactive distillation for synthesis of glycerol carbonate via glycerolysis of urea. Chemical Engineering and Processing: Process Intensification, 70, 103-109.
European Biodiesel Board. 2011. Press Release: 2010-2011: EU biodiesel industry production forecasts show first decrease in 2011 since data is gathered. Available at: https://www.ebbeu.org/EBBpressreleases/EBB%20press%20release%202010%20prod%202011_capacity%20FINAL.pdf. Retrieved 30 July 2020.
กรมพัฒนาพลังงานทดแทนและอนุรักษ์พลังงาน. 2557. ปริมาณการผลิตไบโอดีเซล (B100) ของประเทศไทย. แหล่งข้อมูล : https://www.dede.go.th/more_news.php?cid=88&filename= ind. ค้นเมื่อวันที่ 30 กรกฎาคม 2563.
Pan, S., Zheng, L., Nie, R., Xia, S., Chen, P. and Hou, Z. 2012. Transesterification of Glycerol with Dimethyl Carbonate to Glycerol Carbonate over Na-based Zeolites. Chinese Journal of Catalysis, 33(11-12), 1772–1777.
Sonnati, M.O., Amigoni, S., Elisabeth P. Taffin de Givenchy, Darmanin, T., Choulet, O. and Guittard, F. 2013. Glycerol carbonate as a versatile building block for tomorrow: synthesis, reactivity, properties and applications. Green Chemistry, 2(15), 283–306.
Sandeep, K.L., SreeHarsha, A. and Sidharth, S. 2015. Synthesis and Characterization of 13X Zeolite/ Activated Carbon Composite. International Journal of ChemTech Research, 7(3), 1364-1368.
Mishra, D. 2004. IR X-ray and thermal studies on zeolite-13X and its Mn(II) and Zn(II) exchange and adsorbed derivatives. Studies in Surface Science and Catalysis, 154(Part B), 1693-1699.
Becerraa, M.E., Arias, N.P., Giraldo, O.H., López-Suárez, F.E., Illán-Gómez, M.J. and Bueno-López, A. 2011. Soot combustion manganese catalysts prepared by thermal decomposition of KMnO4. Applied Catalysis B: Environmental, 102(1-2), 260-266.
Chowdam, R., Bijendra, K.S., Krishna, R., Swetha, G., Chandra, S.S., Arvind, G., Gopi, T. and Rao, P.V.L. 2016. Rapid and complete degradation of sulfur mustard adsorbed on M/zeolite-13X supported (M = 5 wt% Mn, Fe, Co) metal oxide catalysts with ozone. RSC Advances, 93(6), 90720-90731.
Gopi, T., Swetha, G., Shekar Chandra, S., Krishna, R., Ramakrishna, C., Saini, Bijendra and Rao, P.V.L. 2019. Ozone catalytic oxidation of toluene over 13X zeolite supported metal oxides and the effect of moisture on the catalytic process. Arabian Journal of Chemistry, 12(8), 4502-4513.
Zijian, Z., Xiaowei, L., Chengpu, L., Xiangkun, E.C. and Minghou, X. 2020. Seawater-assisted synthesis of MnCe/zeolite-13X for removing elemental mercury from coal-fired flue gas. Fuel, 262, 116605.
Huizhong, Z., Zhaoyang, W., Qianwen, L., Tianhao, W., Min, Z. and Qiqi, S. 2020. Water sorption on composite material zeolite 13X modified by LiCl and CaCl2. Microporous and Mesoporous Materials, 299, 110109.
Liguo, W., Yubo, M., Ying, W., Shimin, L. and Youquan, D. 2011. Efficient synthesis of glycerol carbonate from glycerol and urea with lanthanum oxide as a solid base catalyst. Catalysis Communications, 12(15), 1458-1462.
Vanesa, D.B., Concepción, H., María, Á.L., Rafael, G.G., Marina, C.R. and Luis, J.A. 2019. Continuous-flow process for glycerol conversion to solketal using a brönsted acid functionalized carbon-based catalyst. Catalysts, 9(7), 609.
Kondawar, S.E., Mane, R.B., Vasishta, A., More, S.B., Dhengale, S.D. and Rode, C.V. 2017. Carbonylation of glycerol with urea to glycerol carbonate over supported Zn catalysts. Applied Petrochemical Research, 7, 41-53.
Ceri, H., Jose A.L., Mohd, H.A.R., Nikolaos, D., Robert, L.J., Albert, F.C., Qian, H., Christopher, J.K., David, W.K. and Graham, J.H. 2011. Synthesis of glycerol carbonate from glycerol and urea with gold-based catalysts. Dalton Transactions, 15(40), 3927-3937.