การสังเคราะห์อนุภาคนาโนเหล็กเชิงประกอบสารสกัดเปลือกมังคุดโดยวิธีสะอาดเพื่อใช้ในการกำจัดสีย้อมเมทิลีนบลูในสารละลายน้ำ
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มิ.ย. 8, 2019
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อนุภาคนาโนเหล็ก สารสกัดเปลือกมังคุด การสังเคราะห์โดยวิธีสะอาด สีย้อมเมทิลีนบลู
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บทคัดย่อ
บทคัดย่อ
อนุภาคนาโนเหล็กสามารถสังเคราะห์สำเร็จที่อุณหภูมิห้องโดยใช้สารสกัดเปลือกมังคุดทำหน้าที่เป็นตัวรีดิวซ์และสารช่วยเสถียร การศึกษาสภาวะที่เหมาะสมในการสกัดพบว่าเอทานอลร้อยละ 80 เป็นตัวทำละลายที่มีประสิทธิภาพสูงสุดในการสกัดสารประกอบฟีนอลและฟลาโวนอยด์จากเปลือกมังคุด อนุภาคนาโนเหล็กเชิงประกอบสารสกัดเปือกมังคุดสามารถเตรียมโดยวิธีสะอาดจากปฏิกิริยาระหว่างสารละลายเฟอร์ริกไอออนและสารสกัดหยาบในน้ำที่อุณหภูมิห้องเป็นเวลา 12 ชั่วโมง ติดตามการเกิดอนุภาคนาโนโลหะโดยเทคนิคยูวีวิสิเบิลสเปกโทรสโกปี ภาพถ่ายจากกล้องจุลทรรศน์อิเล็กตรอนชนิดส่องผ่านแสดงให้เห็นว่าอนุภาคนาโนเหล็กที่เตรียมได้มีการกระจายตัวที่ดี โดยมีขนาดอนุภาคเฉลี่ยเท่ากับ 12 นาโนเมตร การวิเคราะห์โดยเทคนิคอินฟราเรดสเปกโทรสโกปีสามารถยืนยันแรงกระทำระหว่างหมู่ฟังก์ชันของสารสกัดและอะตอมเหล็กบนพื้นผิวอนุภาค อนุภาคนาโนเหล็กเชิงประกอบสารสกัดเปลือกมังคุดที่สังเคราะห์ได้มีความสามารถสูงในการดูดซับและการรีดักชันเมทิลีนบลู รวมทั้งเป็นตัวเร่งปฏิกิริยาที่มีประสิทธิภาพในการกำจัดสีย้อมเมทิลีนบลูในสารละลายน้ำ
คำสำคัญ : อนุภาคนาโนเหล็ก; สารสกัดเปลือกมังคุด; การสังเคราะห์โดยวิธีสะอาด; สีย้อมเมทิลีนบลู
Article Details
ประเภทบทความ
Physical Sciences
เอกสารอ้างอิง
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[3] Zhao, X., Liu, W., Cai, Z., Han, B., Qian, T., and Zhao, D., 2016, An overview of preparation and applications of stabilized zero-valent iron nanoparticles for soil and groundwater remediation, Water Res. 100: 245-266.
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[7] Shahwan, T., Sirriah, S.A. Nairat, M., Boyaci, E., Eroglu, A.E., Scott, T.B. and Hallam, K.R., 2011, Green synthesis of Iron nanoparticles and their application as a Fenton-like catalyst for the degradation of aqueous cationic and anionic dyes, Chem. Eng. J. 172: 258-266.
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[10] Srikar, S.K., Giri, D.D., Pal, D.B., Mishra, P.K. and Upadhyay, S.N., 2016, Green synthesis of silver nanoparticles: A review, Green Sustain. Chem. 6: 34-56.
[11] Sett, A., Gadewar, M., Sharma, P., Deka, M. and Bora, U., 2016, Green synthesis of gold nanoparticles using aqueous extract of Dillenia indica, Adv. Nat. Sci. Nanosci. Nanotech. 7: 1-8
[12] Herlekar, M., Barve, S. and Kumar, R., 2014, Plant-mediated green synthesis of iron nanoparticles, J. Nanopart. 2014: 1-9.
[13] Pattanayak, M. and Nayak, P.L., 2013, Ecofriendly green synthesis of iron nanoparticles and spiced extract, Int. J. Pl. An. Env. Sci. 3: 68-78.
[14] Rosicka, D. and Sembera, J., 2011, Influence of structure of iron nanoparticles in aggregates on their magnetic properties, Nanoscale Res. Lett. 6: 527.
[15] Dhuper, S., Panda, D. and Nayak, P.L., 2012, Green synthesis and characteriza tion of zero valent iron nanoparticles from the leaf extract of Mangifera indica, Nano Trends J. Nanotechnol. Appl. 13: 16-22.
[16] Karthikeyan, C., Ranjani, M., Kim, A.R., Yoo, D.J. and Kumar, G.G., 2016, Synthesis of iron nanoparticles using Azadirachta indica extract and its catalytic activity toward nitrophenol reduction, J. Nanosci. Nanotechnol. 16: 2527-2533.
[17] Shah, S., Dasgupta, S., Chakraborty, M., Vadakkekara, R. and Hajoori, M., 2014, Green synthesis of iron nanoparticles using plant extracts, Int. J. Biol. Pharm. Res. 5: 549-552.
[18] Kuppusamy, P., Yusoff, M.M., Maniam, G.P. and Govindan, N., 2016, Biosynthesis of metallic nanoparticles using plant derivatives and their new avenues in pharmacological applications: An updated report, Saudi. Pharm. J. 24: 473-484.
[19] Chong, Y.M., Chang, S.K., Sia, W.C.M. and Yim, H.P., 2015, Antioxidant efficacy of mangosteen (Garcinia mangostana Linn.) peel extracts in sunflower oil during accelerated storage, Food Biosci. 12: 18-25.
[20] Lee, K.X., Shameli, K., Miyake, M., Kuwano, N., Khairudin, N.B.A. and Mohamad, S.E., 2016, Green synthesis of gold nanoparticles using aqueous extract of Garcinia mangostana fruit peels, J. Nanomater. 2016: 1-7.
[21] Nastasia, P., Babeş, A. and Bunea, C., 2007, The UV-Vis spectral fingerprints of polyphenols from several red grape varieties, Buletinul USAMV-CN 64: 1454-238.
[22] Doak, J., Gupta, R.K., Manivannan, K., Ghosh, K. and Kahol, P.K., 2010, Effect of particle size distributions on absorbance spectra of gold nanoparticles, Physica E 42: 1605-1609.
[23] He, F. and Zhao, D., 2005, Preparation and characterization of a new class of starch-stabilized bimetallic nanoparticles for degradation of chlorinated hydrocarbons in water, Environ. Sci. Technol. 39: 3314-3320.
[24] Iravani, S. and Zolfaghari, B., 2013, Green synthesis of silver nanoparticles using Pinus eldarica bark extract, BioMed Res. Int. 2013: 1-5.
[25] Suttirak, W. and Manurakchinakorn, S., 2014, In vitro antioxidant properties of mangosteen peel extract, Food Sci. Technol. Int. 51: 3546-3558.
[26] Shan, T., Ma, Q., Guo, K., Liu, J., Li, W., Wang, F. and Wu, E., 2011, Xanthones from mangosteen extracts as natural chemopreventive agents: Potential anticancer drugs, Curr. Mol. Med. 11: 666-677.
[27] Lin, J., Weng, X., Jin, X., Megharaj, M., Naidu, R. and Chen, Z., 2015, Reactivity of iron-based nanoparticles by green synthesis under various atmospheres and their removal mechanism of methylene blue, RSC Adv. 5: 70874-70882.
[2] Naghdi, M., Taheran, M., Brar, S.K., Verma, M., Surampalli, R.Y. and Valero J.R., 2015, Green and energy-efficient methods for the production of metalic nanparticles, Beilstein J. Nanotechnol. 6: 2354-2376.
[3] Zhao, X., Liu, W., Cai, Z., Han, B., Qian, T., and Zhao, D., 2016, An overview of preparation and applications of stabilized zero-valent iron nanoparticles for soil and groundwater remediation, Water Res. 100: 245-266.
[4] Xiao-qin, L., Elliott, D.W. and Wei-xian, Z., 2006, Zero-valent iron nanoparticles for abatement of environmental pollutants: Materials and engineering aspects, Crit. Rev. Solid State Mater. 31: 111-122.
[5] Rafatullah, M., Sulaiman, O., Hashim, R. and Ahmad, A., 2010, Adsorption of methylene blue on low-cost adsorbents: A review, J. Hazard Mater. 177: 70-80.
[6] Dutta, K., Mukhopadhyay, S., Bhattacharjee, S. and Chaudhuri, B., 2001, Chemical oxidation of methylene blue using a Fenton-like reaction, J. Hazard Mater. 84: 57-71.
[7] Shahwan, T., Sirriah, S.A. Nairat, M., Boyaci, E., Eroglu, A.E., Scott, T.B. and Hallam, K.R., 2011, Green synthesis of Iron nanoparticles and their application as a Fenton-like catalyst for the degradation of aqueous cationic and anionic dyes, Chem. Eng. J. 172: 258-266.
[8] Lien, H.L., Elliott, D.W., Sun, Y.P. and Zhang, W.X., 2006, Recent progress in zero-valent iron nanoparticles for groundwater remediation, Environ. Eng. Manag. J. 16: 371-380.
[9] Duan, H., Wang, D. and Li, Y., 2015, Green chemistry for nanoparticle synthesis, Chem. Soc. Rev. 44: 5778-5792.
[10] Srikar, S.K., Giri, D.D., Pal, D.B., Mishra, P.K. and Upadhyay, S.N., 2016, Green synthesis of silver nanoparticles: A review, Green Sustain. Chem. 6: 34-56.
[11] Sett, A., Gadewar, M., Sharma, P., Deka, M. and Bora, U., 2016, Green synthesis of gold nanoparticles using aqueous extract of Dillenia indica, Adv. Nat. Sci. Nanosci. Nanotech. 7: 1-8
[12] Herlekar, M., Barve, S. and Kumar, R., 2014, Plant-mediated green synthesis of iron nanoparticles, J. Nanopart. 2014: 1-9.
[13] Pattanayak, M. and Nayak, P.L., 2013, Ecofriendly green synthesis of iron nanoparticles and spiced extract, Int. J. Pl. An. Env. Sci. 3: 68-78.
[14] Rosicka, D. and Sembera, J., 2011, Influence of structure of iron nanoparticles in aggregates on their magnetic properties, Nanoscale Res. Lett. 6: 527.
[15] Dhuper, S., Panda, D. and Nayak, P.L., 2012, Green synthesis and characteriza tion of zero valent iron nanoparticles from the leaf extract of Mangifera indica, Nano Trends J. Nanotechnol. Appl. 13: 16-22.
[16] Karthikeyan, C., Ranjani, M., Kim, A.R., Yoo, D.J. and Kumar, G.G., 2016, Synthesis of iron nanoparticles using Azadirachta indica extract and its catalytic activity toward nitrophenol reduction, J. Nanosci. Nanotechnol. 16: 2527-2533.
[17] Shah, S., Dasgupta, S., Chakraborty, M., Vadakkekara, R. and Hajoori, M., 2014, Green synthesis of iron nanoparticles using plant extracts, Int. J. Biol. Pharm. Res. 5: 549-552.
[18] Kuppusamy, P., Yusoff, M.M., Maniam, G.P. and Govindan, N., 2016, Biosynthesis of metallic nanoparticles using plant derivatives and their new avenues in pharmacological applications: An updated report, Saudi. Pharm. J. 24: 473-484.
[19] Chong, Y.M., Chang, S.K., Sia, W.C.M. and Yim, H.P., 2015, Antioxidant efficacy of mangosteen (Garcinia mangostana Linn.) peel extracts in sunflower oil during accelerated storage, Food Biosci. 12: 18-25.
[20] Lee, K.X., Shameli, K., Miyake, M., Kuwano, N., Khairudin, N.B.A. and Mohamad, S.E., 2016, Green synthesis of gold nanoparticles using aqueous extract of Garcinia mangostana fruit peels, J. Nanomater. 2016: 1-7.
[21] Nastasia, P., Babeş, A. and Bunea, C., 2007, The UV-Vis spectral fingerprints of polyphenols from several red grape varieties, Buletinul USAMV-CN 64: 1454-238.
[22] Doak, J., Gupta, R.K., Manivannan, K., Ghosh, K. and Kahol, P.K., 2010, Effect of particle size distributions on absorbance spectra of gold nanoparticles, Physica E 42: 1605-1609.
[23] He, F. and Zhao, D., 2005, Preparation and characterization of a new class of starch-stabilized bimetallic nanoparticles for degradation of chlorinated hydrocarbons in water, Environ. Sci. Technol. 39: 3314-3320.
[24] Iravani, S. and Zolfaghari, B., 2013, Green synthesis of silver nanoparticles using Pinus eldarica bark extract, BioMed Res. Int. 2013: 1-5.
[25] Suttirak, W. and Manurakchinakorn, S., 2014, In vitro antioxidant properties of mangosteen peel extract, Food Sci. Technol. Int. 51: 3546-3558.
[26] Shan, T., Ma, Q., Guo, K., Liu, J., Li, W., Wang, F. and Wu, E., 2011, Xanthones from mangosteen extracts as natural chemopreventive agents: Potential anticancer drugs, Curr. Mol. Med. 11: 666-677.
[27] Lin, J., Weng, X., Jin, X., Megharaj, M., Naidu, R. and Chen, Z., 2015, Reactivity of iron-based nanoparticles by green synthesis under various atmospheres and their removal mechanism of methylene blue, RSC Adv. 5: 70874-70882.
