Fabrication of graphene-gold nanoparticles hybrid materials as active catalysts for the degradation of formaldehyde

Authors

  • Sakoolrud Raunmoon Department of Chemistry, Faculty of Science, University of Phayao
  • Thearum Rin Department of Chemistry, Faculty of Science, University of Phayao
  • Waranya Tongin Department of Chemistry, Faculty of Science, University of Phayao
  • Boonyakorn Sonkhayan Department of Chemistry, Faculty of Science, University of Phayao
  • Widsanusan Chartarrayawadee Department of Chemistry, Faculty of Science, University of Phayao

Keywords:

Hybrid materials, Graphene, Gold nanoparticle, Catalyst, Formaldehyde

Abstract

This research studies the fabrication of graphene /gold nanoparticles (AuNPs) hybrid materials by a facile method. To incorporate AuNPs on to graphene, graphene colloidal solution and gold chloride tetrahydrate with various concentration of 1, 4, 8, 40 and 80 weight percent were mixed and stirred overnight at ambient temperature for 24 hours and further reduced with Sodium borohydride. To study the catalytic activity of graphene / AuNPs hybrid materials, the obtained products were subjected to test for the formaldehyde degradation using UV-visible spectroscopy. The study illustrates that graphene / AuNPs hybrid material (8 wt% AuNPs) at pH 10 shows catalytic activities for formaldehyde degradation around 36 percent while the catalytic activities of graphene / AuNPs hybrid materials with 40 and 80 wt% of AuNPs reach more than 80 percent. The obtained products of graphene / AuNPs hybrid materials could be applied as catalyst for the degradation of Formaldehyde in solutions / fluids.

References

Abraham S, König M, Srivastava SK, Kumar V, Walkenfort B, Srivastava A. A Carbon nanostructure (0-3 dimensional) supported isolated gold nanoparticles as an effective SERS substrate. Sens. Actuators 2018;273:455-465.

Ayati A, Ahmadpour A, Bamoharram FF, Tanhaei B, Mänttärid M, Sillanpää M. A review on catalytic applications of Au/TiO2 nanoparticles in the removal of water pollutant. Chemosphere 2014;107:163–174.

Chen FC, Chuang MK, Hsu CS. Gold nanoparticles-graphene oxide nanocomposites that enhance

the device performance of polymer solar cells. Journal of Nanomaterials 2014. Article ID 736879.

Available from https://doi.org/10.1155/2014/736879.

Choi HC, Park Y, Koo JY, Kim S, Choi HC. Spontaneous formation of gold nanoparticles on graphene by galvanic reaction through graphene. ASC Omega 2019;4:18423-18427.

Choucair M, Thordarson P, Stride JA. Gram-scale production of grapheme based on Solvothermal synthesis and sonication. Nat Nano 2009; 4(1):30-33.

Hummer WS, Offeman RE. Preparation of graphite oxide. J Am Chem Soc 1998;80:1339.

Lerf A, He H Y, Forster M, Klinowski J. Structure of graphite oxide revisited. J. Phys. Chem 1998;102:4477-4482.

Li D, Muller MB, Gilje S, Kaner RB, Wallace GG. Processable aqueous dispersions of graphene nanosheets. Nature Nanotechnology 2008;3:101-105.

Lu J, Yang JX, Wang J, Lim A, Wang S, Loh KP. One-Pot synthesis of fluorescent carbon nanoribbons, nanoparticle and graphene by the exfoliation of graphite in ionic liquids. ACS Nano 2009;3(8):2367-2375.

Nepal D, Ren Y, Rao R, Bhusal S, Varshney V, Kedziora G, Wheeler R, Kang Y, Roy A. Hierarchical assembly of gold nanoparticles on graphene nanoplatelets by spontaneous reduction: Implications for smart composites and biosensing. ASC Appl. Nano Mater 2020; 3:8753-8762.

Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV. Electric field effect in atomically thin carbon films. Science 2004;306(5696):666-669.

Pandy PC, Shukla S, Pandy Y. 3-Aminopropyltrimethoxysilane and graphene oxide/reduced graphene oxide-induced generation of gold nanoparticles and their nanocomposites: electrocatalytic and kinetic activity. RSC Adv 2016;6(84).

Park S, Ruoff RS. Chemical methods for the production of graphenes. Nat Nano 2009;4(4):217-224.

Sirajuddin, Mechler A, Torriero AAJ, Nafady A, Lee CY, Bond AM, Mullance APO, Bhargava SK. The formation of gold nanoparticles using hydroquinone as a reducing agent through a localized pH change upon addition of NaOH to a solution of HAuCl4. Colloids and Surfaces 2010;370:35-41.

Movahed SK, Fakharian M, Dabiri M, Bazgir A. Gold nanoparticle decorated reduced graphene oxide sheets with high catalytic activity for Ullmann homocoupling. RSC Adv 2014;4(10):5243-5247.

Zhu X, Cheng B, Yu J, Ho W. Halogen poisoning effect of Pt-TiO2 for formaldehyde catalytic oxidation performance at room temperature. Applied Surface Science 2016;364:808-814.

แสดงกลไกการสลายตัวของฟอร์มาลดีไฮด์ที่เป็นไปได้โดยวัสดุลูกผสมแกรฟีนและอนุภาคทองนาโน

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Published

2023-08-27

How to Cite

1.
Raunmoon S, Rin T, Tongin W, Sonkhayan B, Chartarrayawadee W. Fabrication of graphene-gold nanoparticles hybrid materials as active catalysts for the degradation of formaldehyde. Health Sci Tech Rev [Internet]. 2023 Aug. 27 [cited 2024 Dec. 21];16(2):80-94. Available from: https://li01.tci-thaijo.org/index.php/journalup/article/view/256531

Issue

Vol. 16 No. 2 (2023): May - August

Section

Research articles

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