Physicochemical properties comparison of sugarcane bagasse pith and fiber as solid fuel for biomass power plants
Main Article Content
Abstract
Sugarcane bagasse is the primary fuel used in biomass power plants. However, bagasse contains pith, which is one-third of its composition and has a structure that differs from fiber, which impacts the overall fuel properties of bagasse. Therefore, this research aimed to compare the physicochemical properties of bagasse pith and fiber for use as fuel in biomass power plants. The study began by mechanically separating the bagasse pith from the fiber, followed by analyzing both proximate and ultimate compositions, heating values, thermal decomposition, ash melting behavior, and the chemical composition of the biomass and ash. The results
indicated that bagasse fiber contains higher percentages of fixed carbon, volatile matter, carbon, and hydrogen than pith (14.4, 84.7, 48.4, and 5.8%, respectively). This led to higher heating values for bagasse fiber than pith (19.53 and 14.28 MJ/kg, respectively). Additionally, bagasse fiber had 22.8% less ash content than pith. Bagasse pith contained significantly higher inorganic content than sugarcane fiber in almost all components, especially silicon, which comprised 21.15%, approximately 19 times higher than fiber. Ash from bagasse pith did not melt even at 1,500 °C due to its high SiO2 content of 89.89%, whereas ash from bagasse fiber began to melt at a lower temperature (1,100 °C). The research concludes that bagasse fiber has better fuel properties than pith. This study suggests that consideration should be given to separating the bagasse pith before using the remaining portion as fuel in power plants to reduce ash management issues and improve the thermal properties of bagasse as a fuel. Bagasse pith should be considered for utilization in the paper and packaging industries, as raw material for construction material production, or as soil amendment material in the agricultural sector.
Article Details
References
กองบริหารสื่อองค์การ (2566). กำลังผลิตตามสัญญาของระบบ. การไฟฟ้าฝ่ายผลิตแห่งประเทศไทย.
Camargo, J. M. de O., Ríos, J. M. G., Antonio, G. C., Leite, J. T. C., Camargo, J. M. de O., Ríos, J. M. G., Antonio, G. C., & Leite, J. T. C. (2021). Physicochemical properties of sugarcane industry residues aiming at their use in energy processes. In sugarcane—biotechnology for biofuels. IntechOpen.
Chambon, C. L., Mkhize, T. Y., Reddy, P., Brandt-Talbot, A., Deenadayalu, N., Fennell, P. S., & Hallett, J. P. (2018). Pretreatment of south african sugarcane bagasse using a low-cost protic ionic liquid: A comparison of whole, depithed, fibrous and pith bagasse fractions. Biotechnology for Biofuels, 11(1), 1–16.
Cheng, B.-H., Huang, B.-C., Zhang, R., Chen, Y.-L., Jiang, S.-F., Lu, Y., Zhang, X.-S., Jiang, H., & Yu, H.-Q. (2020). Bio-coal: A renewable and massively producible fuel from lignocellulosic biomass. Science Advances, 6(1), 1–8.
Demirbas, A. (2001). Relationships between lignin contents and heating values of biomass. Energy Conversion and Management, 42(2), 183–188.
Demirbas, A. (2002). Relationships between heating value and lignin, moisture, ash and extractive contents of biomass fuels. Energy Exploration & Exploitation, 20(1), 105–111.
Du, S., Yang, H., Qian, K., Wang, X., & Chen, H. (2014). Fusion and transformation properties of the inorganic components in biomass ash. Fuel, 117, 1281–1287.
Elbersen, W., Lammens, T. M., Alakangas, E. A., Annevelink, B., Harmsen, P., & Elbersen, B. (2017). Chapter 3 - Lignocellulosic biomass quality: matching characteristics with biomass conversion requirements. In C. Panoutsou (Ed.), Modeling and Optimization of Biomass Supply Chains (pp. 55–78). Academic Press.
Fang, X., & Jia, L. (2012). Experimental study on ash fusion characteristics of biomass. Bioresource Technology, 104, 769–774.
Garcia-Maraver, A., Mata-Sanchez, J., Carpio, M., & Perez-Jimenez, J. A. (2017). Critical review of predictive coefficients for biomass ash deposition tendency. Journal of the Energy Institute, 90(2), 214–228.
Horák, J., Kuboňová, L., Dej, M., Laciok, V., Tomšejová, Š., Hopan, F., Krpec, K., & Koloničný, J. (2019). Effects of the type of biomass and ashing temperature on the properties of solid fuel ashes. Polish Journal of Chemical Technology, 21(2), 43–51.
Hrbek, J., Oberndorfer, C., Zanzinger, P., & Pfeifer, C. (2021). Influence of Ca(OH)2 on ash melting behaviour of woody biomass. Carbon Resources Conversion, 4, 84–88.
Kamara, B., Kallon, D. V. V., & Mashinini, P. M. (2022). Fouling and slagging investigation on ash derived from sasol coal using ICP and XRF analytical techniques. Applied Sciences, 12(22), 1–11.
Lois-Correa, J. A. (2012). Depithers for efficient preparation of sugar cane bagasse fibers in pulp and paper industry. Ingeniería, Investigación y Tecnología, 13(4), 417–424.
Megawati, Fardhyanti, D. S., Putri, R. D. A., Fianti, O., Simalango, A. F., & Akhir, A. E. (2018). Synthesis of silica powder from sugar cane bagasse ash and Its application as adsorbent in adsorptive-distillation of ethanol-water solution. MATEC Web of Conferences, 237, 1–6.
Nayak, D. K., Abhilash, P. P., Singh, R., Kumar, R., & Kumar, V. (2022). Fly ash for sustainable construction: A review of fly ash concrete and its beneficial use case studies. Cleaner Materials, 6, 1–35.
Norsuraya, S., Norhasyimi, R., & Fazlena, H. (2017). Characterization of sodium silicate derived from sugarcane bagasse ash. Malaysian Journal of Analytical Science, 21(2), 512–517.
Ozyuguran, A., Akturk, A., & Yaman, S. (2018). Optimal use of condensed parameters of ultimate analysis to predict the calorific value of biomass. Fuel, 214, 640–646.
Palma, K. R. de, Tomaz, E., Soria-Verdugo, A., & Silva, M. A. (2021). The influence of the elemental and structural chemical composition on the ash fusibility of sugarcane bagasse and sugarcane straw. Fuel, 304, 1–14.
Ringdalen, E., & Tangstad, M. (2016). Softening and melting of SiO2, an important parameter for reactions with quartz in Si production. In R. G. Reddy, P. Chaubal, P. C. Pistorius, & U. Pal (Eds.), Advances in molten slags, fluxes, and salts: Proceedings of the 10th International Conference on Molten Slags, Fluxes and Salts 2016 (pp. 43–51). Springer International Publishing.
Rozhina, E., Ishmukhametov, I., Nigamatzyanova, L., Akhatova, F., Batasheva, S., Taskaev, S., Montes, C., Lvov, Y., & Fakhrullin, R. (2021). Comparative toxicity of fly ash: an in vitro study. Molecules, 26(7), 1926.
Sha, D., Li, Y., Zhou, X., Zhang, J., Zhang, H., & Yu, J. (2021). Influence of volatile content on the explosion characteristics of coal dust. ACS Omega, 6(41), 27150–27157.
Suryana, R., Iriani, Y., Nurosyid, F., & Fasquelle, D. (2018). Characteristics of silica rice husk ash from Mojogedang Karanganyar Indonesia. IOP Conference Series: Materials Science and Engineering, 367(1), 012008.
Suttibak, S. (2017). Influence of reaction temperature on yields of bio-oil from fast pyrolysis of sugarcane residues. Engineering and Applied Science Research, 44(3), 142–147.
Takehara, H., Fujiwara, M., Arikawa, M., Diener, M. D., & Alford, J. M. (2005). Experimental study of industrial scale fullerene production by combustion synthesis. Carbon, 43(2), 311–319.
Tian, S., Kang, Z., Chen, L., Fang, Y., Zhuo, Y., & Xu, H. (2017). Characterization of aluminosilicates in fly ashes with different melting points using 27al magic-angel spinning nuclear magnetic resonance. Energy & Fuels, 31(9), 10068–10074.
Wang, H., Cheng, L., Pu, J., & Zhao, J. (2021). Melting characteristics of coal ash and properties of fly ash to understand the slag formation in the shell gasifier. ACS Omega, 6(24), 16066–16075.
Winterbone, D. E., & Turan, A. (2015). Chapter 13—effect of dissociation on combustion parameters. In D. E. Winterbone & A. Turan (Eds.), Advanced thermodynamics for engineers (2nd ed., pp. 295–305). Butterworth-Heinemann.
Xiao, H., Shi ,Hao, Li ,Xinyao, Jiang ,Yanfei, & and Li, J. (2024). Effect of potassium-containing sulfates on high-temperature mineral transformation and coal ash fusibility. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 46(1), 12496–12511.
Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007). Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel, 86(12), 1781–1788.
Yunaidi, Surahmanto, F., & Harnowo, S. (2020). The risk analysis of rice husk of co-firing fuel for boilers in sugar mills. Journal of Physics: Conference Series, 1446(1), 1–8.
Zhang, Y., Li, Q., & Zhou, H. (2016). Chapter 6—effects of ash deposition and slagging on heat transfer. In Y. Zhang, Q. Li, & H. Zhou (Eds.), Theory and Calculation of Heat Transfer in Furnaces (pp. 173–191). Academic Press.