The Kinetic and Thermodynamic Studies of Dyeing Extracted Dye from Cocoa Husk onto Cotton Fabric

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Onjira Jiamsakul
Chutima Septhum

Abstract

The kinetics and thermodynamics of extracted cocoa husk (ECH) dyeing onto cotton fabric were investigated using aluminum ion (Al3+) as a mordant by the meta-mordanting method. Cocoa husk was extracted using water extraction and freeze-drying yielding brown powder. It was shown that the adsorption of ECH onto cotton fabric could be described by a pseudo second-order model indicated that the adsorption process was controlled by chemisorption. In addition, the thermodynamic parameters were calculated. The negative values of Gibbs free energy (∆G°) obtained indicating that the process of adsorption of ECH onto cotton fabric was spontaneous. The enthalpy of formation (∆H°) and the entropy of formation (∆S°) were positive, indicating that they were an endothermic reaction and more disorder of adsorption process, respectively.

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บทความวิจัย (Research Articles)

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